371696

Tetrachloroethylene

anhydrous, ≥99%

• Szinonimák: PCE, Perchloroethylene
• Lineáris képlet: CCl₂=CCl₂
• CAS-szám: 127-18-4
• Molekulatömeg: 165.83
• Beilstein: 1361721
• EC-szám: 204-825-9
• MDL-szám: MFCD00000834
• UNSPSC kód: 12352101
• PubChem Substance ID: 57649708
• NACRES: NA.04

Tulajdonságok

• grade: anhydrous
• Minőségi szint: 100
• gőzsűrűség: 5.83 (vs air)
• gőznyomás: 13 mmHg ( 20 °C); 19 mmHg ( 25 °C)
• Teszt: ≥99%
• form: liquid
• technika/technikák: FTIR: suitable
• szennyeződések: <0.002% water; <0.005% water (100 mL pkg)
• párolgási maradék: <0.0005%
• törésmutató: n20/D 1.505 (lit.)
• bp: 121 °C (lit.)
• mp: −22 °C (lit.)
• oldhatóság: water: soluble 0.15 g/L at 25 °C
• sűrűség: 1.623 g/mL at 25 °C (lit.)
• SMILES string: Cl\C(Cl)=C(\Cl)Cl
• InChI: 1S/C2Cl4/c3-1(4)2(5)6
• Nemzetközi kémiai azonosító kulcs: CYTYCFOTNPOANT-UHFFFAOYSA-N

Leírás

Általános leírás

Tetrachloroethylene (perchloroethylene, PCE), is a chlorinated ethylene compound commonly used as a dry cleaning and degreasing solvent. It shows IR transparency as it has no C–H bonds making it an ideal solvent for IR spectroscopy. PCE is a man-made pollutant which is difficult to degrade. It is a ground water contaminant which has adverse effect on human health due to its potential toxicity and carcinogenicity. Some of the methods proposed for its degradation are Fenton oxidation treatment, reductive dehalogenation under methanogenic condition, and reduction using zero valent metal ions. One of the methods reported for its synthesis is from ethylene dichloride and chlorine.

Alkalmazás

Tetrachloroethylene may be used as a film-forming electrolyte additive in the manufacture of lithium ion batteries. It may also be used as an extractant for the estimation of oil and grease in water by Fourier transform infrared spectroscopy (FT-IR).

Tetrachloroethylene may be used as a starting material in the synthesis of unsym.-heptachloropropane. It may also be used as a solvent in the preparation of 1-chloro-1-(trichloroethenyl)cyclopropane from tetrachlorocyclopropene and ethylene.

Biztonsági adatok

• Piktogramok: GHS08,GHS07,GHS09
• Figyelmeztetés: Warning
• Figyelmeztető mondatok: H315,H317,H319,H336,H351,H411
• Óvintézkedésre vonatkozó mondatok: P202 - P273 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313
• Veszélyességi osztályok: Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
• Célzott szervek: Central nervous system
• Tárolási osztály kódja: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Lobbanási pont (F): No data available
• Lobbanási pont (C): No data available
• Egyéni védőeszköz: Eyeshields, Gloves, type ABEK (EN14387) respirator filter