4-(Diphenylphosphino)benzoic acid is a phosphine ligand that is employed in palladium-catalyzed cross-coupling and Suzuki cross-coupling reactions.[1][2]
Alkalmazás
4-(Diphenylphosphino)benzoic acid can be used as a ligand in the synthesis of:
Organostannoxane-supported palladium nanoparticles. The resulting catalysts show high activity and selectivity in Suzuki-coupling reactions.[3]
Polymetallic ruthenium-zinc complex catalyst for the hydrogenation of levulinic acid to γ-valerolactone.[4]
Glucosamine-based phosphines. Efficient ligands in the Suzuki cross-coupling reaction in water
Parisot S, et al.
Tetrahedron Letters, 43(41), 7397-7400 (2002)
Organostannoxane-supported palladium nanoparticles. Highly efficient catalysts for suzuki-coupling reactions
Chandrasekhar V, et al.
Organometallics, 28(20), 5883-5888 (2009)
Predicting the stereochemistry of diphenylphosphino benzoic acid (DPPBA)-based palladium-catalyzed asymmetric allylic alkylation reactions: a working model
Trost BM, et al.
Accounts of Chemical Research, 39(10), 747-760 (2006)
As the size of nanoparticles (NPs) is in the range of biological molecules and subcellular structures, they provide new perspectives in biomedicine. This work presents studies concerning the cellular uptake and distribution of phosphine-stabilized cytotoxic 1.4 nm sized AuNPs and
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