Accounts of chemical research, 41(11), 1450-1460 (2008-08-14)
Copper-assisted Ullmann-type coupling reactions are valuable transformations for organic synthesis. Researchers have extensively applied these reactions in both academic and industrial settings. However, two important issues, the high reaction temperatures (normally above 150 degrees C) and the stoichiometric amounts of
Self-assembly of nanometer-scale [Cu24I10L12]14+ cages and ball-shaped Keggin clusters into a (4,12)-connected 3D framework with photoluminescent and electrochemical properties.
Xin-Long Wang et al.
Angewandte Chemie (International ed. in English), 45(44), 7411-7414 (2006-11-07)
Fabrication of an Efficient Solid-State Dye-Sensitized Solar Cell
Journal of the American Chemical Society, 128(43), 14156-14165 (2006-10-26)
Conventional metal-catalyzed organic radical reactions and living radical polymerizations (LRP) performed in nonpolar solvents, including atom-transfer radical polymerization (ATRP), proceed by an inner-sphere electron-transfer mechanism. One catalytic system frequently used in these polymerizations is based on Cu(I)X species and N-containing