Passa al contenuto
Merck
  • Determination of solubility parameters of ionic liquids and ionic liquid/solvent mixtures from intrinsic viscosity.

Determination of solubility parameters of ionic liquids and ionic liquid/solvent mixtures from intrinsic viscosity.

Chemphyschem : a European journal of chemical physics and physical chemistry (2014-08-26)
Piyarat Weerachanchai, Yuewen Wong, Kok Hwa Lim, Timothy Thatt Yang Tan, Jong-Min Lee
ABSTRACT

The total and partial solubility parameters (dispersion, polar and hydrogen-bonding solubility parameters) of ten ionic liquids were determined. Intrinsic viscosity approaches were used that encompassed a one-dimensional method (1D-Method), and two different three-dimensional methods (3D-Method1 and 3D-Method2). The effect of solvent type, the dimethylacetamide (DMA) fraction in the ionic liquid, and dissolution temperature on solubility parameters were also investigated. For all types of effect, both the 1D-Method and 3D-Method2 present the same trend in the total solubility parameter. The partial solubility parameters are influenced by the cation and anion of the ionic liquid. Considering the effect on partial solubility parameters of the solvent type in the ionic liquid, it was observed that in both 3D methods, the dispersion and polar parameters of a 1-ethyl-3-methylimidazolium acetate/solvent (60:40 vol %) mixture tend to increase as the total solubility parameter of the solvent increases.

MATERIALI
N° Catalogo
Marchio
Descrizione del prodotto

Sigma-Aldrich
Metanolo, suitable for HPLC, ≥99.9%
Sigma-Aldrich
Dimetil solfossido, Hybri-Max, sterile-filtered, BioReagent, suitable for hybridoma, ≥99.7%
Sigma-Aldrich
2-Propanolo, suitable for HPLC, 99.9%
Sigma-Aldrich
Dimetil solfossido, ACS reagent, ≥99.9%
Sigma-Aldrich
Dimetil solfossido, for molecular biology
Sigma-Aldrich
2-Propanolo, ACS reagent, ≥99.5%
Sigma-Aldrich
Ethyl alcohol, Pure, 200 proof, ACS reagent, ≥99.5%
Sigma-Aldrich
Metanolo, ACS reagent, ≥99.8%
Sigma-Aldrich
Dimetil solfossido, suitable for HPLC, ≥99.7%
Sigma-Aldrich
N,N-dimetilformammide, ACS reagent, ≥99.8%
Sigma-Aldrich
N,N-dimetilformammide, suitable for HPLC, ≥99.9%
Sigma-Aldrich
Dimetil solfossido, sterile-filtered, BioPerformance Certified, meets EP, USP testing specifications, suitable for hybridoma
Sigma-Aldrich
Dimetil solfossido, ReagentPlus®, ≥99.5%
Sigma-Aldrich
Metanolo, HPLC Plus, ≥99.9%
Sigma-Aldrich
1-propanolo, suitable for HPLC, ≥99.9%
Sigma-Aldrich
1-butanolo, 99.9%
Sigma-Aldrich
Ethyl alcohol, Pure, 200 proof, meets USP testing specifications
Sigma-Aldrich
Dimetil solfossido, ≥99.5% (GC), suitable for plant cell culture
Sigma-Aldrich
Ethyl alcohol, Pure, 190 proof, for molecular biology
Sigma-Aldrich
2-Propanolo, HPLC Plus, for HPLC, GC, and residue analysis, 99.9%
Sigma-Aldrich
1-butanolo, ACS reagent, ≥99.4%
Sigma-Aldrich
2-Propanolo, meets USP testing specifications
Sigma-Aldrich
Metanolo, suitable for HPLC, gradient grade, suitable as ACS-grade LC reagent, ≥99.9%
Sigma-Aldrich
2-Propanolo, for molecular biology, BioReagent, ≥99.5%
Sigma-Aldrich
1-butanolo, suitable for HPLC, ≥99.7%
Sigma-Aldrich
2-Propanolo, Laboratory Reagent, ≥99.5%
Sigma-Aldrich
Metanolo, Laboratory Reagent, ≥99.6%
Sigma-Aldrich
Etanolo, BioUltra, for molecular biology, ≥99.8%, (absolute alcohol, without additive, A15 o1)
Sigma-Aldrich
2-Butanol, ReagentPlus®, ≥99%
Sigma-Aldrich
N,N-dimetilformammide, ReagentPlus®, ≥99%