414247

2-Methyltetrahydrofuran

BioRenewable, anhydrous, ≥99.0%, contains 250 ppm BHT as stabilizer

• Sinônimo(s): 2-MeTHF, Tetrahydro-2-methylfuran, Tetrahydrosilvan
• Fórmula empírica (Notação de Hill): C₅H₁₀O
• Número CAS: 96-47-9
• Peso molecular: 86.13
• Beilstein: 102448
• Número CE: 202-507-4
• Número MDL: MFCD00005367
• Código UNSPSC: 12352005
• ID de substância PubChem: 57650057
• NACRES: NA.07

Propriedades

• grau: anhydrous
• Nível de qualidade: 100
• Ensaio: ≥99.0%
• forma: liquid
• contém: 250 ppm BHT as stabilizer
• Lim. expl.: 0.34-6.3 %
• características do produto alternativo mais ecológico: Safer Solvents and Auxiliaries; Use of Renewable Feedstocks; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Impurezas: <0.002% water; <0.005% water (100 mL pkg)
• resíduo de evaporação: <0.0003%
• índice de refração: n20/D 1.406 (lit.)
• pb: 78-80 °C (lit.)
• pf: -136 °C
• densidade: 0.86 g/mL at 25 °C (lit.)
• categoria alternativa mais ecológica: Aligned,
• cadeia de caracteres SMILES: CC1CCCO1
• InChI: 1S/C5H10O/c1-5-3-2-4-6-5/h5H,2-4H2,1H3
• chave InChI: JWUJQDFVADABEY-UHFFFAOYSA-N

Descrição

Descrição geral

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is a biorenewable and thus aligns with "Safer Solvents and Auxiliaries" and "Use of Renewable Feedstocks". Click here for more information.
2-Methyltetrahydrofuran (2-MTHF), a 2-methyl substituted tetrahdrofuran, is a biomass derived solvent. It is a potential greener solvent alternative for organic synthesis. It shows resistance to reduction by lithium making it a promising candidate as electrolytes in lithium batteries. Its polarity and Lewis base strength is intermediate between tetrahydrofuran (THF) and diethyl ether. The ring opening reaction of 2-MTHF has been studied using acid chloride and iodide to form secondary chlorides and primary iodides respectively. On long term storage, tetrahydrofuran forms organic peroxides. This process can be suppressed by adding butylated hydroxytoluene (BHT) as a stabilizer. BHT removes the free radicals required for the peroxide formation.

Aplicação

2-Methyltetrahydrofuran may be used as solvent for phosphatidylserine synthesis.
It may be used as an alternative solvent to:

• DMSO (dimethyl sulfoxide) or MTBE (methyl tertiary butyl ether) in the C-C bond forming reactions catalyzed by lyase enzyme.
• THF in the reaction between Grignard reagents and carbonyl compounds.
• Methylene chloride in some biphase reactions.

Green Alternatives to DCM and THF from Renewable Resources

Organic Solar Cells

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Características e benefícios

Greener alternative for THF, DCM, DMSO, and MTBE

Embalagem

View returnable container options.

Outras notas

Pure-Pac^® II containers require the Micromatic MacroValve coupler for dispensing solvents, Z560723.

Informações legais

Pure-Pac is a registered trademark of Merck KGaA, Darmstadt, Germany

Informações de segurança

• Pictogramas: GHS02,GHS05,GHS07
• Palavra indicadora: Danger
• Frases de perigo: H225,H302,H315,H318
• Declarações de precaução: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Classificações de perigo: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2
• Perigos de suplementos: EUH019
• Código de classe de armazenamento: 3 - Flammable liquids
• Classe de risco de água (WGK): WGK 2
• Ponto de fulgor (°F): 14.0 °F - closed cup
• Ponto de fulgor (°C): -10.0 °C - closed cup
• Equipamento de proteção individual: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter