D187208
2,5-Dimethyltetrahydrofuran, mixture of cis and trans
96%
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About This Item
Fórmula empírica (Notação de Hill):
C6H12O
Número CAS:
Peso molecular:
100.16
Beilstein:
102563
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22
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Nível de qualidade
Ensaio
96%
Formulário
liquid
índice de refração
n20/D 1.404 (lit.)
p.e.
90-92 °C (lit.)
densidade
0.833 g/mL at 25 °C (lit.)
cadeia de caracteres SMILES
CC1CCC(C)O1
InChI
1S/C6H12O/c1-5-3-4-6(2)7-5/h5-6H,3-4H2,1-2H3
chave InChI
OXMIDRBAFOEOQT-UHFFFAOYSA-N
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Categorias relacionadas
Palavra indicadora
Warning
Frases de perigo
Classificações de perigo
Flam. Liq. 3
Código de classe de armazenamento
3 - Flammable liquids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
80.6 °F - closed cup
Ponto de fulgor (°C)
27 °C - closed cup
Equipamento de proteção individual
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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M S Akhlaq et al.
International journal of radiation biology and related studies in physics, chemistry, and medicine, 51(1), 91-102 (1987-01-01)
Thiyl radicals (RS) formed by the reaction of radiolytically generated OH radicals with thiols, e.g. 1,4-dithiothreitol (DTT), react with cis- and trans-2,5-dimethyltetrahydrofuran by abstracting an H atom in the alpha-position to the ether function (k approximately equal to 5 X
Matthew R Grochowski et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(39), 12363-12371 (2012-08-24)
Carbohydrates, such as fructose, can be fully dehydroxylated to 2,5-dimethyltetrahydrofuran (DMTHF), a valuable chemical and potential gasoline substitute, by the use of a dual catalytic system consisting of HI and RhX(3) (X=Cl, I). A mechanistic study has been carried out
Weiran Yang et al.
ChemSusChem, 3(5), 597-603 (2010-05-04)
Existing technologies to produce liquid fuels from biomass are typically energy-intensive, multistep processes. Many of these processes use edible biomass as starting material. Carbohydrates, such as mono- and polysaccharides and cellulose, typically constitute 50-80% of plant biomass. Herein, we report
John M Simmie
The journal of physical chemistry. A, 116(18), 4528-4538 (2012-04-13)
The enthalpies of formation, entropies, specific heats at constant pressure, enthalpy functions, and all carbon-hydrogen and carbon-methyl bond dissociation energies have been computed using high-level methods for the cyclic ethers (oxolanes) tetrahydrofuran, 2-methyltetrahydrofuran, and 2,5-dimethyltetrahydrofuran. Barrier heights for hydrogen-abstraction reactions
A S Anderson et al.
The Journal of organic chemistry, 65(15), 4648-4654 (2000-08-26)
2'-Deoxy-5-methyleneuridin-5-yl (1) is produced in a variety of DNA damage processes and is believed to result in the formation of lesions that are mutagenic and refractory to enzymatic repair. 2'-Deoxy-5-methyleneuridin-5-yl (1) was independently generated under anaerobic conditions via Norrish Type
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