905305

(S,S,S)-SPIRAP

≥95%

• 別名: ((1S,3S,3′S)-3,3′-diethyl-3H,3′H-1,1′-spirobi[isobenzofuran]-7,7′-diyl)bis(diphenylphosphane), (S)-CrabPhos
• 実験式（ヒル表記法）: C₄₃H₃₈O₂P₂
• 分子量: 648.71
• UNSPSCコード: 12161600

特性

• アッセイ: ≥95%
• フォーム: powder or crystals
• 反応適合性: reaction type: Asymmetric synthesis; reagent type: ligand
• mp: 226-228 °C
• 官能基: phosphine
• SMILES記法: CC[C@H](O1)C2=C([C@@]1(O[C@@H]3CC)C4=C3C=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6)C(P(C7=CC=CC=C7)C8=CC=CC=C8)=CC=C2

詳細

アプリケーション

(S,S,S)-SPIRAP is a chiral C₂-symmetric spiroketal-containing ligand developed in the Nagorny lab for asymmetric catalysis. It can be used in variety of stereoselective transformations, including: Ir-catalyzed hydroarylation, Pd-catalyzed allylic alkylation, Pd-catalyzed Heck couplings, and Rh-catalyzed hydrogenation.[1]

Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

その他情報

Design, Synthesis, and Application of Chiral C₂-Symmetric Spiroketal-Containing Ligands in Transition-Metal Catalysis

安全性情報

• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable