The inner packaging has undergone a hydrostatic pressure test. For the amber glass bottle PM1305 with SureSeal crown cap PM3314, a hydrostatic pressure test is conducted at 66 psi to ensure no leakage from the container.
製品175552は現在お客様の国では販売されていません。 製品に関するお問い合わせはこちら（テクニカルサービス）
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蒸気密度
1 (vs air)
品質水準
蒸気圧
9.75 psi ( 20 °C)
アッセイ
99%
フォーム
liquid
expl. lim.
70 %
bp
32-34 °C (lit.)
密度
1.342 g/mL at 25 °C (lit.)
保管温度
2-8°C
SMILES記法
Cl[SiH](Cl)Cl
InChI
1S/Cl3HSi/c1-4(2)3/h4H
InChI Key
ZDHXKXAHOVTTAH-UHFFFAOYSA-N
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詳細
Trichlorosilane is used as a reducing agent in certain chemical reactions or as a starting material for the synthesis of various organosilicon compounds. Trichlorosilane is generally used for the asymmetric hydrosilylation of olefins in the presence of palladium catalysts coordinated with chiral monodentate phosphorus ligands to generate chiral organosilanes.[1]
アプリケーション
Trichlorosilane has been used to synthesize 11-dicyclohexylphosphino-12-phenyl-9,10-dihydro-9,10-ethenoanthracene (H-KITPHOS) via reduction of 11-dicyclohexylphosphinoyl-12-phenyl-9,10-dihydro-9,10-ethenoanthracene.[2]
Other possible applications:
L-valine-derived catalyst to form secondary amines.[3]
derivatives is an effective reagent for the reduction of imines to form
enantiomerically enriched amines.[5][6]
Other possible applications:
- Asymmetric reduction of N-aryl ketimines in the presence of a novel
L-valine-derived catalyst to form secondary amines.[3]
- Hydrosilylation of imidazolinones to form chiral imidazolidinones in the presence of a 2,2′-bispyrrolidine based Lewis base organocatalyst.[4]
- Trichlorosilane activated with chiral N-formylproline
derivatives is an effective reagent for the reduction of imines to form
enantiomerically enriched amines.[5][6]
- Trichlorosilane reacts with dimethylformamide to form hypervalent hydridosilicates, which can reduce aldehydes to alcohols, imines to amines, and also for the reductive amination of aldehydes. [7]
シグナルワード
Danger
危険有害性情報
危険有害性の分類
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1A - Water-react 1
補足的ハザード
保管分類コード
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 1
引火点(°F)
<-2.2 °F - Equilibrium method
引火点(℃)
< -19 °C - Equilibrium method
個人用保護具 (PPE)
Faceshields, Gloves, Goggles
適用法令
試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。
毒物及び劇物取締法
劇物
消防法
第3類:自然発火性物質及び禁水性物質
塩素化けい素化合物
危険等級I
第一種自然発火性物質及び禁水性物質
労働安全衛生法名称等を表示すべき危険物及び有害物
名称等を表示すべき危険物及び有害物
労働安全衛生法名称等を通知すべき危険物及び有害物
名称等を通知すべき危険物及び有害物
Jan Code
175552-100G:4548173109220
175552-250G:
175552-VAR:
175552-PZ:
175552-10KG:
175552-500G:4548173109237
175552-5G:4548173109244
175552-BULK:
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Christophe Blaszykowski et al.
Langmuir : the ACS journal of surfaces and colloids, 28(5), 2318-2322 (2012-01-25)
We report herein three unprecedented alkyltrichlorosilane surface modifiers bearing pentafluorophenyl ester (PFP), benzothiosulfonate (BTS), or novel β-propiolactone (BPL) functionalizable terminal groups. Evidence is provided that these molecules can be prepared in very high purity (as assessed by NMR) through a
Wei Ouyang et al.
Proceedings of the National Academy of Sciences of the United States of America, 116(33), 16240-16249 (2019-07-31)
Rapid and reliable detection of ultralow-abundance nucleic acids and proteins in complex biological media may greatly advance clinical diagnostics and biotechnology development. Currently, nucleic acid tests rely on enzymatic processes for target amplification (e.g., PCR), which have many inherent issues
Yaosi Fang et al.
Advanced science (Weinheim, Baden-Wurttemberg, Germany), 7(13), 2000310-2000310 (2020-07-17)
As an analogue to the vapor-liquid-solid process, the solution-liquid-solid (SLS) method offers a mild solution-phase route to colloidal 1D nanostructures with controlled sizes, compositions, and properties. However, direct growth of 1D nanostructure arrays through SLS processes remains in its infancy.
New organic activators for the enantioselective reduction of aromatic imines with trichlorosilane
Onomura O
Tetrahedron Letters, 47(22), 3751-3754 (2006)
First chemo-and stereoselective reduction of imines using trichlorosilane activated with N-formylpyrrolidine derivatives
Iwasaki F
Tetrahedron Letters, 42(13), 2525-2527 (2001)
アクティブなフィルタ
ライフサイエンス、有機合成、材料科学、クロマトグラフィー、分析など、あらゆる分野の研究に経験のあるメンバーがおります。.
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