コンテンツへスキップ
Merck
すべての画像(1)

主要文書

すべての文書を表示

安全性情報

175552

Sigma-Aldrich

トリクロロシラン

99%

別名:

Hydrotrichlorosilane, Silicochloroform, Silicon chloride hydride, Trichloromonosilane

ログイン組織・契約価格を表示する
すべての画像(1)

About This Item

化学式:
SiHCl3
CAS番号:
10025-78-2
分子量:
135.45
EC Number:
233-042-5
MDL番号:
MFCD00011518
UNSPSCコード:
12352101
PubChem Substance ID:
24850509
NACRES:
NA.22
製品175552は現在お客様の国では販売されていません。 製品に関するお問い合わせはこちら（テクニカルサービス）

蒸気密度

1 (vs air)

品質水準

200

蒸気圧

9.75 psi ( 20 °C)

アッセイ

99%

フォーム

liquid

expl. lim.

70 %

bp

32-34 °C (lit.)

密度

1.342 g/mL at 25 °C (lit.)

保管温度

2-8°C

SMILES記法

Cl[SiH](Cl)Cl

InChI

1S/Cl3HSi/c1-4(2)3/h4H

InChI Key

ZDHXKXAHOVTTAH-UHFFFAOYSA-N

類似した製品をお探しですか？ 訪問 製品比較ガイド

関連するカテゴリー

詳細

Trichlorosilane is used as a reducing agent in certain chemical reactions or as a starting material for the synthesis of various organosilicon compounds. Trichlorosilane is generally used for the asymmetric hydrosilylation of olefins in the presence of palladium catalysts coordinated with chiral monodentate phosphorus ligands to generate chiral organosilanes.[1]

アプリケーション

Trichlorosilane has been used to synthesize 11-dicyclohexylphosphino-12-phenyl-9,10-dihydro-9,10-ethenoanthracene (H-KITPHOS) via reduction of 11-dicyclohexylphosphinoyl-12-phenyl-9,10-dihydro-9,10-ethenoanthracene.[2]
Other possible applications:
  • Asymmetric reduction of N-aryl ketimines in the presence of a novel

L-valine-derived catalyst to form secondary amines.[3]
  • Hydrosilylation of imidazolinones to form chiral imidazolidinones in the presence of a 2,2′-bispyrrolidine based Lewis base organocatalyst.[4]
  • Trichlorosilane activated with chiral N-formylproline

derivatives is an effective reagent for the reduction of imines to form
enantiomerically enriched amines.[5][6]
  • Trichlorosilane reacts with dimethylformamide to form hypervalent hydridosilicates, which can reduce aldehydes to alcohols, imines to amines, and also for the reductive amination of aldehydes. [7]

ピクトグラム

FlameSkull and crossbonesCorrosion
GHS02,GHS06,GHS05

シグナルワード

Danger

危険有害性情報

H224,H260,H302,H314,H331

危険有害性の分類

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1A - Water-react 1

補足的ハザード

EUH014,EUH029,EUH071

保管分類コード

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 1

引火点(°F)

<-2.2 °F - Equilibrium method

引火点(℃)

< -19 °C - Equilibrium method

個人用保護具 (PPE)

Faceshields, Gloves, Goggles

適用法令

試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。

毒物及び劇物取締法

劇物

消防法

第3類:自然発火性物質及び禁水性物質
塩素化けい素化合物
危険等級I
第一種自然発火性物質及び禁水性物質

労働安全衛生法名称等を表示すべき危険物及び有害物

名称等を表示すべき危険物及び有害物

労働安全衛生法名称等を通知すべき危険物及び有害物

名称等を通知すべき危険物及び有害物

Jan Code

175552-100G:4548173109220
175552-250G:
175552-VAR:
175552-PZ:
175552-10KG:
175552-500G:4548173109237
175552-5G:4548173109244
175552-BULK:

最新バージョンのいずれかを選択してください：

試験成績書（COA）

Lot/Batch Number
STBL4371
SHBR9747
STBL4968
SHBR5523
STBL2803

適切なバージョンが見つかりませんか。

特定のバージョンが必要な場合は、ロット番号またはバッチ番号で特定の証明書を検索できます。

COAを検索

以前この製品を購入いただいたことがある場合

文書ライブラリで、最近購入した製品の文書を検索できます。

文書ライブラリにアクセスする

この製品を見ている人はこちらもチェック

Slide 1 of 5

1 of 5

Octenyltrichlorosilane, mixture of isomers 96%

Sigma-Aldrich

539279

Octenyltrichlorosilane, mixture of isomers

トリエトキシシラン 95%

Sigma-Aldrich

390143

トリエトキシシラン

クロロジメチルシラン 98%

Sigma-Aldrich

144207

クロロジメチルシラン

Silicon tetrachloride for synthesis

Sigma-Aldrich

8.07706

Silicon tetrachloride

ジヨードシラン contains copper as stabilizer

Sigma-Aldrich

339873

ジヨードシラン

Amira Namsi et al.
Molecules (Basel, Switzerland), 24(18) (2019-09-14)
Neurodegenerative diseases are characterized by oxidative stress, mitochondrial damage, and death of neuronal cells. To counteract such damage and to favor neurogenesis, neurotrophic factors could be used as therapeutic agents. Octadecaneuropeptide (ODN), produced by astrocytes, is a potent neuroprotective agent.
Trichlorosilane-dimethylformamide (Cl3SiH-DMF) as an efficient reducing agent. Reduction of aldehydes and imines and reductive amination of aldehydes under mild conditions using hypervalent hydridosilicates
Kobayashi S
Chemistry Letters (Jpn), 25(5), 407-408 (1996)
An J J Ver Heyen et al.
Small (Weinheim an der Bergstrasse, Germany), 4(8), 1160-1167 (2008-07-25)
A second-generation polyphenylene dendrimer 1 is shown to self-assemble into nanofibers. To guide the formation of the dendrimer fibers into well-defined patterns, 1H,1H,2H,2H-perfluorodecyltrichlorosilane is grafted in the gas phase onto a silicon substrate. De-wetting of the solution on the nanopatterned
Christophe Blaszykowski et al.
Langmuir : the ACS journal of surfaces and colloids, 28(5), 2318-2322 (2012-01-25)
We report herein three unprecedented alkyltrichlorosilane surface modifiers bearing pentafluorophenyl ester (PFP), benzothiosulfonate (BTS), or novel β-propiolactone (BPL) functionalizable terminal groups. Evidence is provided that these molecules can be prepared in very high purity (as assessed by NMR) through a
Trinh Lam et al.
Scientific reports, 7(1), 1188-1188 (2017-04-28)
A chemically patterned microfluidic paper-based analytical device (C-µPAD) is developed to create fluidic networks by forming hydrophobic barriers using chemical vapor deposition (CVD) of trichlorosilane (TCS) on a chromatography paper. By controlling temperature, pattern size, and CVD duration, optimal conditions
関連する文献をすべて表示

質問

1–4/4 質問  

  1. Are all quantities of HSiCl3 sold in sure seal bottles?

    1 回答

    1. Yes, each quantity of this product is packaged using SureSeal closures.

      役に立ちましたか？

  2. How can I determine the shelf life / expiration / retest date of this product?

    1 回答

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      役に立ちましたか？

  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 回答

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      役に立ちましたか？

  4. Do you have any pressure specifications for the SureSeal bottles in C20927043, particularly for product 175552-500G?

    1 回答

    1. The inner packaging has undergone a hydrostatic pressure test. For the amber glass bottle PM1305 with SureSeal crown cap PM3314, a hydrostatic pressure test is conducted at 66 psi to ensure no leakage from the container.

      役に立ちましたか？

レビュー

評価値なし

アクティブなフィルタ

ライフサイエンス、有機合成、材料科学、クロマトグラフィー、分析など、あらゆる分野の研究に経験のあるメンバーがおります。.

製品に関するお問い合わせはこちら（テクニカルサービス）