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Sigma-Aldrich

Potassium tetrachloroplatinate(II)

≥99.9% trace metals basis

Sinônimo(s):

Potassium platinum(II) chloride

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About This Item

Fórmula linear:
K2PtCl4
Número CAS:
Peso molecular:
415.09
Número CE:
Número MDL:
Código UNSPSC:
12352302
ID de substância PubChem:
NACRES:
NA.23

Nível de qualidade

Ensaio

≥99.9% trace metals basis

forma

powder or crystals

composição

Pt, ≥46.2%

Impurezas

≤1000.0 ppm Trace Metal Analysis

densidade

3.38 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

[K+].[K+].Cl[Pt--](Cl)(Cl)Cl

InChI

1S/4ClH.2K.Pt/h4*1H;;;/q;;;;2*+1;+2/p-4

chave InChI

RVRDLMCWUILSAH-UHFFFAOYSA-J

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Descrição geral

Potassium tetrachloroplatinate(II) is a crystalline solid that is insoluble in water and soluble in organic solvents. It is widely used in the field of nanomaterial synthesis, catalysis, and energy storage.

Aplicação

Potassium tetrachloroplatinate(II) can be used:
  • As a precursor to prepare platinum nanoparticles and mesoporous platinum nanospheres with tunable pore sizes.
  • As a catalyst for selective methane oxidation through C-H activation. In addition, to synthesize octahedral Pd@Pt1.8Ni nanocrystals with an ultrathin PtNi alloy shell. The nanocrystals exhibited better ORR activity and durability than the commercial Pt/C for fuel cells.
  • To prepare Pt atomic clusters were synthesized using a one-step carbon-defect-driven electroless deposition method. These catalysts demonstrated low overpotential, high activity for the hydrogen evolution reaction, exceptional stability, and improved utilization efficiency of Pt. The Pt-AC/DG (Atomic Clusters/Defective Graphene) cathode showed excellent hydrogen production activity, remarkable stability, and significantly reduced Pt usage compared to the Pt/C catalyst.
  • As a starting material to synthesize cyclometalated platinum(II) complexes with long-lived luminescence in solution.

Características e benefícios

Reacts with bis(dithiolates) to form metal-bis(dithiolates) with applications in laser Q-switch materials, liquid crystals, optical CD recording media, bar code materials and superconductivity. Reacts with capping polymers to form shape-control colloidal platinum nanoparticles for catalysis and photocatalysts.

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1

Código de classe de armazenamento

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


Certificados de análise (COA)

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Visite a Biblioteca de Documentos

Alkyl chain functionalised, cyclometalated platinum(II) complexes: Syntheses, luminescence properties and X-ray crystal structure
Juliette A. Lowe, et al.
Journal of Organometallic Chemistry, 805, 87-93 (2016)
Carbon-Defect-Driven Electroless Deposition of Pt Atomic Clusters for Highly Efficient Hydrogen Evolution
Qingqing Cheng, et al.
Journal of the American Chemical Society, 142, 5594-5601 (2020)
Polymeric micelle assembly for the smart synthesis of mesoporous platinum nanospheres with tunable pore sizes
Yunqi Li, et al.
Angewandte Chemie (International Edition in English), 54, 11073-11077 (2015)
Selective Methane Oxidation Catalyzed by Platinum Salts in Oleum at Turnover Frequencies of Large-Scale Industrial Processes
Tobias Zimmermann, et al.
Journal of the American Chemical Society, 138, 12395-12400 (2016)
E Thanasias et al.
Advances in experimental medicine and biology, 755, 47-53 (2012-07-25)
Allergic immediate-type reactions by halogenated compounds of platinum (Pt) (platinum salts) have been described in workers in precious metal refineries and catalyst productions. In both industries there are exposures to many different Pt compounds. It is believed that the most

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