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Merck

276855

Sigma-Aldrich

Dimethylsulfoxid

Dimethyl sulfoxide

anhydrous, ≥99.9%

Synonym(e):

DMSO, Methylsulfoxid

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About This Item

Lineare Formel:
(CH3)2SO
CAS-Nummer:
Molekulargewicht:
78.13
Beilstein:
506008
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12191502
PubChem Substanz-ID:
Qualität:
anhydrous
Assay:
≥99.9%
bp:
189 °C (lit.)
Dampfdruck:
0.42 mmHg ( 20 °C)
Preise und Verfügbarkeit sind derzeit nicht verfügbar.

Qualität

anhydrous

Qualitätsniveau

Dampfdichte

2.7 (vs air)

Dampfdruck

0.42 mmHg ( 20 °C)

Assay

≥99.9%

Form

liquid

Selbstzündungstemp.

573 °F

Expl.-Gr.

42 %, 63 °F

Verunreinigungen

<0.005% water

Abdampfrückstand

<0.0005%

Farbe

colorless

Brechungsindex

n20/D 1.479 (lit.)

bp

189 °C (lit.)

mp (Schmelzpunkt)

16-19 °C (lit.)

Löslichkeit

H2O: miscible (completely)

Dichte

1.10 g/mL (lit.)

SMILES String

CS(C)=O

InChI

1S/C2H6OS/c1-4(2)3/h1-2H3

InChIKey

IAZDPXIOMUYVGZ-UHFFFAOYSA-N

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Allgemeine Beschreibung

Dimethylsulfoxid ist ein apolares, protisches Lösungsmittel[1], das allgemein als Reaktionsmedium und Reagens in organischen Reaktionen eingesetzt wird.[2][3]

Anwendung

Dimethylsulfoxid kann als Oxidationsmittel bei der Umsetzung von Isonitrilen zu Isocyanaten eingesetzt werden.[4] Durch Oxalylchlorid aktiviertes DMSO kann bei der Oxidation von langkettigen Alkoholen zu Carbonylen eingesetzt werden.[5]

Verpackung

18 l, 200 l in Pure-Pac®-Edelstahlbehältern; 100 ml, 250 ml, 1 l, 2 l, 6×1 l in Sure/Seal®-Flaschen

Vorsicht

Unterkühlt leicht und schmilzt langsam bei Raumtemperatur. Das verfestigte Produkt kann durch Erwärmen auf Raumtemperatur wieder verflüssigt werden, ohne dabei geschädigt zu werden.

Sonstige Hinweise

Die Artikelnummer 276855-4X2L wird eingestellt. Bestellen Sie stattdessen bitte die Einzelflasche 276855-2L, die physisch identisch ist und genau dieselben Spezifikationen aufweist.
Informationen zur Mischbarkeit von Dimethylsulfoxid finden Sie unter folgendem Link:
Tabelle zur Mischbarkeit/Unmischbarkeit von Dimethylsulfoxid
Pure-Pac®-II-Behälter erfordern ein Micromatic-MacroValve-Verbindungsstück (Z560723) zur Entnahme von Lösungsmitteln.

Rechtliche Hinweise

Pure-Pac is a registered trademark of Merck KGaA, Darmstadt, Germany

Lagerklassenschlüssel

10 - Combustible liquids

WGK

WGK 1

Flammpunkt (°F)

188.6 °F - closed cup

Flammpunkt (°C)

87 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Analysenzertifikate (COA)

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Kunden haben sich ebenfalls angesehen

A Practical Synthesis of Isocyanates from Isonitriles: Ethyl 2-Isocyanatoacetate
Hoang VLe and Ganem B
Organic Syntheses, 89, 404-404 (2012)
Dimethyl sulfoxide oxidations.
Epstein WW & Sweat FW.
Organic Syntheses, 67(3), 247-260 (1967)
The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologicals
Royal Society of Chemistry null
Oxidation of long-chain and related alcohols to carbonyls by dimethyl sulfoxide" activated" by oxalyl chloride.
Mancuso AJ, et al.
The Journal of Organic Chemistry, 43(12), 2480-2482 (1978)
Young-Keun Yang et al.
Nature protocols, 2(7), 1740-1745 (2007-07-21)
This protocol describes detailed procedures for the preparation of a rhodamine-based mercury probe and for its applications to the detection of mercury in cells and vertebrate organisms. The mercury probe 1, which is prepared in two steps from rhodamine 6G

Artikel

TiO2 exhibits wide band gap semiconductor and memristor properties electronically, with high opacity and UV absorbance optically.

Questions

1–10 of 12 Questions  
  1. can i use it in cell culturing

    1 answer
    1. This product has not been tested for suitability in cell culture. Please see the link below to review cell culture tested DMSO product options:
      https://www.sigmaaldrich.com/product/sigma/d2650
      https://www.sigmaaldrich.com/product/sigma/d2438
      https://www.sigmaaldrich.com/product/sigma/d4540

      Helpful?

  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  4. Hello, I am Kui. I bought a DMSO anhydrous solvent from Sigma Aldrich Inc (CAS#: 67-68-5). I would like to know if there is inert gas inside the bottle. What kind of inert gas is it? Many thanks

    1 answer
    1. Yes, this product is flushed with nitrogen.

      Storage information can be accessed in the SDS available at this link: https://www.sigmaaldrich.com/US/en/sds/sial/276855

      Helpful?

  5. What is Sure/Seal™ packaging?

    1 answer
    1. The Aldrich Sure/Seal™ packaging system is useful in the handling and storage of air-sensitive reagents.

      Helpful?

  6. Where does DMSO come from?

    1 answer
    1. DMSO is known to have been isolated from tree bark in the past. It is now a commericially synthesized solvent.

      Helpful?

  7. What is the DMSO dissolved in?

    1 answer
    1. DMSO is not dissolved in any solvent. It is a pure chemical compound that is a liquid at room temperature.

      Helpful?

  8. Dimethyl sulfoxide (DMSO) should be a liquid.  Why did it arrive as a solid?

    1 answer
    1. DMSO supercools easily, and re-melts slowly at room temperature. The melting point is 16-19 °C. The solidified product can be re-liquefied by warming to room temperature without detriment to the product.

      Helpful?

  9. What is the molarity of DMSO?

    1 answer
    1. DMSO will have a molarity of 14.1M, based on a density of 1.1 g/mL and a molecular weight of 78.13 g/mol.

      Helpful?

  10. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

      Helpful?

1–10 of 12 Questions  

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