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8.14371

Triethylamine trishydrofluoride

for synthesis

Synonim(y):

Triethylamine trishydrofluoride

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Gabaryty przesyłkiSKUDostępnośćCena netto
2 mL
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97,00 zł
10 mL
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271,00 zł

Informacje o tej pozycji

Wzór liniowy:
(C2H5)3N · 3 HF
Numer CAS:
Masa cząsteczkowa:
161.21
UNSPSC Code:
12352107
EC Index Number:
277-550-5
NACRES:
NA.22
MDL number:
Form:
liquid

97,00 zł


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Quality Segment

form

liquid

pH

3 (20 °C in H2O, saturated aqueous solution)

bp

70 °C/19.9 hPa

transition temp

flash point 88 °C

density

1.00 g/cm3 at 20 °C

storage temp.

2-30°C

SMILES string

[F-].[F-].[F-].[N+H](CC)(CC)CC.[H+].[H+]

InChI

1S/C6H15N.3FH/c1-4-7(5-2)6-3;;;/h4-6H2,1-3H3;3*1H

InChI key

IKGLACJFEHSFNN-UHFFFAOYSA-N

Application

  • Asymmetric synthesis of fluoroamines from chiral aziridines: This study explores the use of triethylamine trishydrofluoride in the synthesis of fluoroamines, highlighting its role in enhancing reaction selectivity and efficiency (Park et al., 2014).
  • Recent advance in the synthesis of (1, 1-difluoroethyl) arenes: This paper discusses recent advancements in the synthesis of difluoroethyl arenes using triethylamine trishydrofluoride, contributing to the development of new fluorination techniques (Li et al., 2018).
  • Quantification of hydrogen fluoride-based reagents using a bifunctional NMR internal standard: Describes the quantification of reagents like triethylamine trishydrofluoride in chemical syntheses, emphasizing the accuracy of measurement techniques (Hammond et al., 2016).
  • Extensive CRISPR RNA modification reveals chemical compatibility and structure-activity relationships for Cas9 biochemical activity: This research utilizes triethylamine trishydrofluoride for RNA modifications in CRISPR-Cas9 processes, showing its potential in genetic engineering (O′Reilly et al., 2019).

Analysis Note

Assay (HClO₄): ≥ 98.0 %
Colour (visual): colourless, almost colourless
Density (d 20 °C/ 4 °C): 0.995 - 1.000
Identity (IR): passes test
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Ta pozycja
8.211358.211778.08352
Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

300

storage temp.

2-30°C

storage temp.

2-30°C

storage temp.

2-30°C

storage temp.

2-30°C

form

liquid

form

powder

form

liquid

form

liquid

bp

70 °C/19.9 hPa

bp

-

bp

30.8 °C

bp

90 °C/1013 hPa

density

1.00 g/cm3 at 20 °C

density

1.07 g/cm3 at 21 °C

density

0.88 g/cm3 at 20 °C

density

0.73 g/cm3 at 20 °C

transition temp

flash point 88 °C

transition temp

-

transition temp

flash point -45 °C

transition temp

flash point -11 °C


pictograms

CorrosionSkull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Eye Dam. 1 - Skin Corr. 1A

Klasa składowania

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

190.4 °F

flash_point_c

88 °C



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Numer pozycji handlu globalnego

SKUNUMER GTIN
814371001004022536412832
814371000204027269276843

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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