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440167

Sigma-Aldrich

(3-Glycidyloxypropyl)trimethoxysilane

≥98%

Synonim(y):

3-(2,3-Epoxypropoxy)propyltrimethoxysilane, GLYMO, Glycidyl 3-(trimethoxysilyl)propyl ether

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100 ML
279,00 zł
500 ML
1130,00 zł
1 L
2350,00 zł
2.5 L
5470,00 zł

279,00 zł

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Wszystkie zdjęcia(1)

Wybierz wielkość

Zmień widok
100 ML
279,00 zł
500 ML
1130,00 zł
1 L
2350,00 zł
2.5 L
5470,00 zł

About This Item

Wzór empiryczny (zapis Hilla):
C9H20O5Si
Numer CAS:
2530-83-8
Masa cząsteczkowa:
236.34
Beilstein:
4308125
Numer WE:
219-784-2
Numer MDL:
MFCD00005144
Kod UNSPSC:
12352103
Identyfikator substancji w PubChem:
24867573
NACRES:
NA.23

279,00 zł

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Poziom jakości

200

Próba

≥98%

Formularz

liquid

współczynnik refrakcji

n20/D 1.429 (lit.)

bp

120 °C/2 mmHg (lit.)

gęstość

1.07 g/mL at 25 °C (lit.)

ciąg SMILES

CO[Si](CCCOCC1CO1)(OC)OC

InChI

1S/C9H20O5Si/c1-10-15(11-2,12-3)6-4-5-13-7-9-8-14-9/h9H,4-8H2,1-3H3

Klucz InChI

BPSIOYPQMFLKFR-UHFFFAOYSA-N

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Opis ogólny

(3-Glycidyloxypropyl)trimethoxysilane (GPTMS) is a bifunctional organosilane with three methoxy groups on one side and an epoxy ring on the other. The methoxy groups bind well with glass substrates creating a 3D matrix. The epoxy group is reactive with amides, alcohols, thiols and acids. GPTMS is highly reactive in water and can be used as a linking agent between the surface of the silica and the polymeric matrix.[1][2][3]

Zastosowanie

GPTMS is widely used as a silica precursor. GPTMS alone with tetraethylortosilicate (TEOS) can be blended with chitosan for use as a filler for polymeric scaffold for bone tissue engineering.[4] It can also be coated on the surface of aluminium alloy to protect from corrosion.[5] GPTMS can used to functionalize (wrap) multi-walled carbon nanotubes (MWCNTs) which can be used as s a reinforcement in epoxy matrix nanocomposites.[2]
Pre-treatment of carbon steel with 3-(Glycidoxypropyl)trimethoxysilane enhances the dry and wet adhesion while reducing the cathotic disbondment rate of an epoxy coating[6]
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Piktogramy

Corrosion
GHS05

Hasło ostrzegawcze

Danger

Zwroty wskazujące rodzaj zagrożenia

H318,H412

Zwroty wskazujące środki ostrożności

P273 - P280 - P305 + P351 + P338 - P501

Klasyfikacja zagrożeń

Aquatic Chronic 3 - Eye Dam. 1

Kod klasy składowania

10 - Combustible liquids

Klasa zagrożenia wodnego (WGK)

WGK 1

Temperatura zapłonu (°F)

235.4 °F - closed cup

Temperatura zapłonu (°C)

113 °C - closed cup

Środki ochrony indywidualnej

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

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Certyfikaty analizy (CoA)

Lot/Batch Number
SDBB1794
SDBB1793
SDBB0475
STBL0642
STBL2731

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Masz już ten produkt?

Dokumenty związane z niedawno zakupionymi produktami zostały zamieszczone w Bibliotece dokumentów.

Odwiedź Bibliotekę dokumentów

Journal of the Chemical Society. Perkin Transactions 1, 729-729 (1997)
Journal of Organometallic Chemistry, 625, 208-208 (2001)
Effect of (3-glycidyloxypropyl) trimethoxysilane (GOPS) on the electrical properties of PEDOT: PSS films.
kansson H, et al.
Journal of Polymer Science. Part B, Polymer Physics, 55(10), 814-820 (2017)
Harun, M.K.; et al.
Progress in Organic Coatings, 4, 317-317 (2005)
Ahmed A Nada et al.
International journal of biological macromolecules, 133, 538-544 (2019-04-22)
Homogenous allocation of inorganic particles in a polymeric matrix is a challenge. In this work, we discuss electrospinning of chitosan /gelatin using CS-Si (chitosan silicone hybrids) as well as the formation of homogeneously distributed Zn elements inside chitosan nanofiber through
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Produkty

Synthesis of Melting Gels Using Mono-Substituted and Di-Substituted Alkoxysiloxanes

Hybrid organic-inorganic sol-gel materials containing silica were first called “ORMOSILs” in 1984.

Questions

1–9 of 9 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  3. I would like to know the solvent for GPTMS. What solvents does GPTMS dispersed in?

    1 answer

    1. This product is supplied as a neat or pure liquid with a density of 1.07 g/mL. The minimum purity is 98%. This compound is soluble in water, alcohols, acetone, and most aliphatic esters at normal application levels of 45%.

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  4. I connected  GPTMS synthetically to my lipid(APTES), now my lipid cannot be dissolved in chloroform, ethanol and methanol solutions, which was previously dissolved, what solvent should I use?

    1 answer

    1. The solubility of the GPTMS/APTES sample has not been tested, however decreasing the concentration in chloroform may be useful. Other solvents such as oils (see C8267) or a strong base, such as sodium hydroxide, may also be an option. See the link below to a publication that may be of interest:
      https://pubs.acs.org/doi/10.1021/acssuschemeng.9b06741

      If you have any further issues, please contact https://www.sigmaaldrich.com/techservice, click on "Product Technical Inquiries" under the Products Section, and provide the required information so that a member of the Technical Service team can reach out to assist further. Thank you.

      Helpful?

  5. What is the Department of Transportation shipping information for this product?

    1 answer

    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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  6. What is the viscosity of Product 440167 (3-Glycidyloxypropyl)trimethoxysilane GLYMO?

    1 answer

    1. This material is a low viscosity liquid with an average value of about 3 centistokes. Please note that this value is not part of our specifications.

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  7. Is Product 440167 (3-Glycidyloxypropyl)trimethoxysilane GLYMO, equivalent to Dow's Z-6040?

    1 answer

    1. Yes. This listing is manufactured by Dow Corning Corporation and distributed by Sigma-Aldrich.

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  8. What can Product 440167, 3-Glycidyloxypropyl)trimethoxysilane GLYMO, be used for?

    1 answer

    1. According to Dow Corning®, 3-GLYCIDOXYPROPYLTRIMETHOXYSILANE can be used as a coupling agent for many thermoset resins with glass or  mineral fillers. Specifically, it has been used as a reinforcement treatment on glass fiber to improve physical properties (especially wet strength) or as  an adhesion promoter to improve the bonding of a polymer coating or adhesive to glass, metals or other polymeric surfaces.

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  9. Where can I find more detailed information about how to use Product 440167. 3-Glycidyloxypropyl)trimethoxysilane, GLYMO, in adhesion/reinforcement applications?

    1 answer

    1. Dow Corning® has published a technical bulletin on this product, which is available by calling Technical Service at 800-231-8327.

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