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Merck

323446

Sigma-Aldrich

Ammonium tetrathiomolybdate

99.97% trace metals basis

Synonim(y):

Ammonium thiomolybdate, Diammonium tetrathiomolybdate

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1 G
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50 G
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1 G
278,00 zł
10 G
1030,00 zł
50 G
3730,00 zł

About This Item

Wzór liniowy:
(NH4)2MoS4
Numer CAS:
Masa cząsteczkowa:
260.28
Numer MDL:
Kod UNSPSC:
12352302
Identyfikator substancji w PubChem:
NACRES:
NA.23

278,00 zł


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Poziom jakości

Próba

99.97% trace metals basis

Formularz

crystalline

przydatność reakcji

reagent type: catalyst
core: molybdenum

zanieczyszczenia

≤350.0 ppm Trace Metal Analysis

mp

>300 °C (lit.)

ciąg SMILES

[NH4+].[NH4+].[S-][Mo]([S-])(=S)=S

InChI

1S/Mo.2H3N.4S/h;2*1H3;;;;/q;;;;;2*-1/p+2

Klucz InChI

PQNOIAHNKHBLRN-UHFFFAOYSA-P

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Zastosowanie

Ring opening of aziridines leading to sulfides and disulfides.[1]
This classic building block for transition metal sulfide cluster compounds was recently used in a low-temperature, solid state synthesis of a new series of heterometallic sulfide clusters stabilized with dppm [bis(diphenylphosphino)methane] ligands.[2]

Działania biochem./fizjol.

Acts as a chelator in vivo to reduce copper levels. Tetrathiomolybdate interferes with angiogenesis and reduces tumor growth. Its mechanism may involve inhibition of NF-κB and downstream cytokines.[3]
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Kod klasy składowania

13 - Non Combustible Solids

Klasa zagrożenia wodnego (WGK)

WGK 3

Temperatura zapłonu (°F)

Not applicable

Temperatura zapłonu (°C)

Not applicable

Środki ochrony indywidualnej

Eyeshields, Gloves, type N95 (US)


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Certyfikaty analizy (CoA)

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Dokumenty związane z niedawno zakupionymi produktami zostały zamieszczone w Bibliotece dokumentów.

Odwiedź Bibliotekę dokumentów

Yu Lei et al.
Science advances, 6(32), eabc4250-eabc4250 (2020-08-22)
Two-dimensional transition metal dichalcogenides (TMDs) emerged as a promising platform to construct sensitive biosensors. We report an ultrasensitive electrochemical dopamine sensor based on manganese-doped MoS2 synthesized via a scalable two-step approach (with Mn ~2.15 atomic %). Selective dopamine detection is
George J Brewer
Current cancer drug targets, 5(3), 195-202 (2005-05-17)
Tetrathiomolybdate (TM) is a novel anticopper agent under development for use in Wilson's disease. It acts by forming a stable tripartite complex with serum albumin and copper, rendering the complexed copper unavailable for cellular uptake. TM is a very potent
Satoru Yamasaki et al.
The Journal of cell biology, 177(4), 637-645 (2007-05-16)
Zinc is an essential trace element required for enzymatic activity and for maintaining the conformation of many transcription factors; thus, zinc homeostasis is tightly regulated. Although zinc affects several signaling molecules and may act as a neurotransmitter, it remains unknown
Devarajulu Sureshkumar et al.
The Journal of organic chemistry, 72(6), 2106-2117 (2007-02-24)
A comprehensive study of a general and effective one-step procedure for the synthesis of beta-sulfonamidodisulfides directly from N-tosyl aziridines in a regio- and stereospecific manner under neutral conditions without the use of any Lewis acid or base has been reported.
Pengfei Cao et al.
Scientific reports, 7(1), 16048-16048 (2017-11-24)
Amorphous molybdenum sulfide/carbon black (MoS

Produkty

Ultrasonic spray pyrolysis produces scalable nanomaterials like metal oxides and quantum dots for diverse applications.

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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