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For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
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253189
Tris(diethylamino)phosphine
97%, liquid
Synonim(y):
Hexaethyltriamidophosphite, Hexaethyltriaminophosphine, Phosphorous acid tris(diethylamide), Tris(N,N-diethylamino)phosphine, Tris(diethylamido)phosphine, Hexaethylphosphorous triamide
Wybierz wielkość
| Rozmiar/SKU | Dostępność | Cena netto |
|---|---|---|
5 g | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 366,00 zł |
25 g | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 862,00 zł |
Informacje o tej pozycji
366,00 zł
Nazwa produktu
Tris(diethylamino)phosphine, 97%
Quality Segment
assay
97%
form
liquid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
refractive index
n20/D 1.475 (lit.)
bp
80-90 °C/10 mmHg (lit.)
density
0.903 g/mL at 25 °C (lit.)
functional group
phosphine
SMILES string
CCN(CC)P(N(CC)CC)N(CC)CC
InChI
1S/C12H30N3P/c1-7-13(8-2)16(14(9-3)10-4)15(11-5)12-6/h7-12H2,1-6H3
InChI key
FDIOSTIIZGWENY-UHFFFAOYSA-N
Application
- 1,1′-Dialkylisoindigo derivatives by reacting with various 1-alkylisatins via deoxygenation reaction.
- 1-Aminomethylisatins by treating with isatin and primary and secondary amines.
It can also be used in the deoxygenation of some cyclic α-diketones using fullerene C60.
1 of 1
Ta pozycja | |||
|---|---|---|---|
| description 97% | description 97% | description 90% | description 95% |
| reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Sonogashira Coupling, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reagent type: ligand, reaction type: Heck Reaction, reaction type: Suzuki-Miyaura Coupling, reaction type: Stille Coupling | reaction suitability reagent type: ligand | reaction suitability reaction type: Heck Reaction, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reagent type: ligand, reaction type: Suzuki-Miyaura Coupling, reaction type: Stille Coupling, reaction type: Hiyama Coupling | reaction suitability reaction type: Negishi Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand |
| functional group phosphine | functional group phosphine | functional group phosphine | functional group phosphine |
| form liquid | form liquid | form - | form powder |
| Quality Level 200 | Quality Level 100 | Quality Level 200 | Quality Level 100 |
| density 0.903 g/mL at 25 °C (lit.) | density 0.898 g/mL at 25 °C (lit.) | density - | density - |
| bp 80-90 °C/10 mmHg (lit.) | bp 48-50 °C/12 mmHg (lit.) | bp 111-113 °C/2.5 mmHg (lit.) | bp - |
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Klasa składowania
3 - Flammable liquids
flash_point_f
138.2 °F - closed cup
flash_point_c
59 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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