Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
Kluczowe dokumenty
223670
Bis(cyclopentadienyl)zirconium(IV) chloride hydride
95%
Synonim(y):
Di(cyclopentadienyl)zirconium(IV) chloride hydride, Schwartz’ reagent, Zirconocene chloride hydride
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255,00 zł
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About This Item
255,00 zł
Polecane produkty
Poziom jakości
Próba
95%
Formularz
powder
przydatność reakcji
core: zirconium
reagent type: catalyst
reagent type: reductant
ciąg SMILES
[H][Zr]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI
1S/2C5H5.ClH.Zr.H/c2*1-2-4-5-3-1;;;/h2*1-5H;1H;;/q;;;+1;/p-1
Klucz InChI
PSYHEBZUPSHSKK-UHFFFAOYSA-M
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Opis ogólny
Zastosowanie
- To convert amides to aldehydes.[2]
- As a reagent for the functionalization of olefins and alkynes.[3]
- As a reducing agent in the preparation of (E)-vinyl organochalcogenides.[4]
- To prepare a dioxaborolane derivative, which is a key intermediate for the synthesis of bridged-nicotine analogs.[5]
Hasło ostrzegawcze
Danger
Zwroty wskazujące rodzaj zagrożenia
Zwroty wskazujące środki ostrożności
Klasyfikacja zagrożeń
Skin Corr. 1B - Water-react 2
Kod klasy składowania
4.3 - Hazardous materials which set free flammable gases upon contact with water
Klasa zagrożenia wodnego (WGK)
WGK 3
Środki ochrony indywidualnej
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfHelpful?
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