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Merck

151882

Sigma-Aldrich

Deuterium oxide

Deuterium oxide
1 of 3 reviewers received a sample product or took part in a promotion

99.9 atom % D

Synonim(y):

Heavy water, Water-d2

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10 X 0.6 ML
257,00 zł
10 X 1 ML
344,00 zł
100 G
1120,00 zł
500 G
5080,00 zł

257,00 zł


Przewidywany termin wysyłki03 marca 2025Szczegóły


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10 X 0.6 ML
257,00 zł
10 X 1 ML
344,00 zł
100 G
1120,00 zł
500 G
5080,00 zł

About This Item

Wzór empiryczny (zapis Hilla):
D2O
Numer CAS:
Masa cząsteczkowa:
20.03
Numer WE:
Numer MDL:
Kod UNSPSC:
12142201
Identyfikator substancji w PubChem:
NACRES:
NA.21
metody:
NMR: suitable
bio NMR: suitable
bp:
101.4 °C (lit.)

257,00 zł


Przewidywany termin wysyłki03 marca 2025Szczegóły


Poproś o zamówienie zbiorcze

czystość izotopowa

99.9 atom % D

Poziom jakości

Formularz

liquid

metody

NMR: suitable
bio NMR: suitable

bp

101.4 °C (lit.)

mp

3.8 °C (lit.)

temp. przechowywania

room temp

ciąg SMILES

[2H]O[2H]

InChI

1S/H2O/h1H2/i/hD2

Klucz InChI

XLYOFNOQVPJJNP-ZSJDYOACSA-N

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Opis ogólny

Deuterium oxide, a deuterated solvent,[1] is a standard prurity solvent for NMR (Nuclear Magnetic Resonance) analyses. Various thermodynamic properties (such as intermolecular vibrational frequencies, energy of the hydrogen bond, free energy, enthalpy and entropy) of liquid deuterium oxide have been evaluated.[2] Ionization constant for D2O (in the range of 5-50°C), pK values (at 25°C) and enthalpy, entropy, heat capacity change (for the dissociation of D2O) have been reported.[3]

Zastosowanie

Deuterium oxide (Heavy water, Water-d2, D2O) has been used as solvent for the dissolution of internal standard and sample during quantification experiments by NMR.[1] It has been used for the dissolution of tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate Ru(bpy)3.4
Deuterium oxide may be used:
  • To prepare trifluoroacetic acid-d by reacting with trifluoroacetic anhydride.[4]
  • As a deuteration agent for primary and secondary alcohols at the β-carbon position via H/D exchange reaction in the presence of ruthenium catalyst.[5]
  • Along with hexamethyldisilane as a deuterium transfer reagent for alkynes to form (E)-1,2-dideuterioalkenes in the presence of a palladium complex.[6]

Polecane produkty

Check out ChemisTwin®, our brand new online portal for identity confirmation and quantification of NMR spectra. Learn more or reach out to us for a free trial.
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Kod klasy składowania

12 - Non Combustible Liquids

Klasa zagrożenia wodnego (WGK)

nwg

Temperatura zapłonu (°F)

Not applicable

Temperatura zapłonu (°C)

Not applicable


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Certyfikaty analizy (CoA)

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Masz już ten produkt?

Dokumenty związane z niedawno zakupionymi produktami zostały zamieszczone w Bibliotece dokumentów.

Odwiedź Bibliotekę dokumentów

Muidh Alheshibri et al.
Journal of colloid and interface science, 537, 123-131 (2018-11-14)
Robust methods for differentiating long-lived nanobubbles from other nanoparticles are required. Evaluation of the density and compressibility of nanoparticles should enable nanobubbles to be differentiated from other nanoparticles, although the response of nanobubbles to pressure can be strongly influenced by
Ruthenium-Catalyzed Regioselective Deuteration of Alcohols at the ?-Carbon Position with Deuterium Oxide.
Tse SKS, et al.
Chemistry?A European Journal , 17(49), 13918-13925 (2011)
Useful NMR solvent mixture for polyesters: Trifluoroacetic acid-d/chloroform-d.
Hariharan R and Pinkus AG.
Polym. Bull., 30(1), 91-95 (1993)
Structure of water and hydrophobic bonding in proteins. IV. The thermodynamic properties of liquid deuterium oxide.
Nemethy G and Scheraga HA.
J. Chem. Phys. , 41(3), 680-689 (1964)
Ling Rong Wong et al.
Biomedicines, 8(12) (2020-12-16)
Accumulating evidence suggests that disruptions in brain energy metabolism may be a key player in the pathogenesis of Alzheimer's disease (AD). Pioglitazone (PIO) has been found to exert beneficial effects on metabolic dysfunction in many AD preclinical studies. However, limited

Produkty

Use this reference table to find the coupling values and chemical shifts of our NMR (deuterated) solvents. Melting and boiling points, molecular weight, density, and CAS number are also listed.

Skorzystaj z tej tabeli referencyjnej, aby znaleźć wartości sprzężenia i przesunięcia chemiczne naszych rozpuszczalników NMR (deuterowanych). Wymienione są również temperatury topnienia i wrzenia, masa cząsteczkowa, gęstość i numer CAS.

Powiązane treści

NMR spectroscopy elucidates molecular structure and purity via nuclear spin states in a strong magnetic field.

Spektroskopia NMR wyjaśnia strukturę molekularną i czystość poprzez stany spinu jądrowego w silnym polu magnetycznym.

Questions

1–6 of 6 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. Does this product (Cat. No 151882) contain propionic acid (C₃H₆O₂)?

    1 answer
    1. This product does not contain propionic acid. Deuterium preprarations that include propionic acid may be reviewed at the link below:
      https://www.sigmaaldrich.com/search/deuterium-propionate?focus=products&page=1&perpage=30&sort=relevance&term=deuterium%20propionate&type=product

      Helpful?

  4. I don't have the ability to store Product 151882, Deuterium oxide, under nitrogen to prevent H2O uptake. Is there another way that I can work with D20 in order to preserve its purity?

    1 answer
    1. You may be interested in our ampulized deuterium oxide products: 521965 (10x0.6mL), 441376 (10x0.75mL) or 269794 (10x1mL). These products are ideal for one time use applications, like as an NMR solvent, because there is decreased chance of water uptake during storage.

      Helpful?

  5. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

      Helpful?

  6. How should I store Product 151882, Deuterium oxide, to preserve its purity?

    1 answer
    1. According to our MSDS, deuterium oxide is classified as hygroscopic and should be stored under an inert gas like nitrogen, to prevent hydrogenated water uptake.

      Helpful?

Reviews

1 of 3 reviewers received a sample product or took part in a promotion

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  1. 3 Ratings-Only Reviews

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