656577

1,3-Diisopropylimidazolium chloride

97%

• 別名: N,N'-(イソプロピル)イミダゾリウム クロリド
• 実験式（ヒル表記法）: C₉H₁₇ClN₂
• CAS番号: 139143-09-2
• 分子量: 188.70
• MDL番号: MFCD03840577
• UNSPSCコード: 12352005
• PubChem Substance ID: 24884209
• NACRES: NA.22

特性

• アッセイ: 97%
• 形状: solid
• 反応適合性: reagent type: catalyst
• 環境により配慮した代替製品の特徴: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 182-186 °C
• 環境により配慮した代替製品カテゴリ: Aligned,
• SMILES記法: [Cl-].CC(C)n1cc[n+](c1)C(C)C
• InChI: 1S/C9H17N2.ClH/c1-8(2)10-5-6-11(7-10)9(3)4;/h5-9H,1-4H3;1H/q+1;/p-1
• InChI Key: DOFXKPAOJLLPII-UHFFFAOYSA-M

詳細

詳細

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

アプリケーション

1,3-Diisopropylimidazolium chloride may be used to prepare:

• 1,3-Diisopropylimidazole-2-thione by reacting with sulfur in the presence of potassium carbonate.
• (C₉H₇)NiCl(1,3-diisopropylimidazol-2- ylidene) by reacting with bis-indenyl nickel-(II).
• Ruthenium N-heterocyclic carbene complexes, which are efficient catalysts for the amidation of primary alcohols and amines.

Ligand for ruthenium-catalyzed greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H315,H319,H335
• 注意書き: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): dust mask type N95 (US), Eyeshields, Gloves