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904767

Sigma-Aldrich

[Ru(phen)3]Cl2

≥95%

Sinonimo/i:

Dichlorotris(1,10-phenanthroline)ruthenium(II) chloride

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100 MG
85,50 €
250 MG
195,00 €

85,50 €

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100 MG
85,50 €
250 MG
195,00 €

About This Item

Formula empirica (notazione di Hill):
C36H24Cl2N6Ru
Numero CAS:
23570-43-6
Peso molecolare:
712.59
Numero MDL:
MFCD00061374
Codice UNSPSC:
12352101
NACRES:
NA.22

85,50 €

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Richiedi un ordine bulk

Saggio

≥95%

Stato

powder or crystals

Impiego in reazioni chimiche

core: ruthenium
reagent type: catalyst
reaction type: Photocatalysis

Punto di fusione

>300 °C

Stringa SMILE

[Ru+2]951([NH]%10=C%11C%12=[NH]9C=CC=C%12C=CC%11=CC=C%10)([NH]6=C7C8=[NH]5C=CC=C8C=CC7=CC=C6)[NH]2=C3C4=[NH]1C=CC=C4C=CC3=CC=C2.[Cl-].[Cl-]

InChI

1S/3C12H8N2.2ClH.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;;/h3*1-8H;2*1H;/q;;;;;+2/p-2
UWXWBVKIJZGXQL-UHFFFAOYSA-L

Categorie correlate

Applicazioni

[Ru(phen)3]Cl2 is a cyclometalated ruthenium complex that can be used in visible light mediated photocatalytic organic transformations.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Altre note

Photocatalysis Tech Spotlight

Visible-Light-Mediated Decarboxylative Radical Additions to Vinyl Boronic Esters: Rapid Access to -Amino Boronic Esters

Prodotti correlati

N° Catalogo
Descrizione
Determinazione del prezzo

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

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Certificati d'analisi (COA)

Lot/Batch Number
MKCS2328
MKCP6084
MKCN3490

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Chelsea A Huff et al.
The Journal of organic chemistry, 81(16), 6980-6987 (2016-06-18)
We report the development of a method for room-temperature C-H hydroxymethylation of heteroarenes. A key enabling advance in this work was achieved by implementing visible light photoredox catalysis that proved to be applicable to many classes of heteroarenes and tolerant
Tanmay Chatterjee et al.
The Journal of organic chemistry, 81(16), 6995-7000 (2016-06-22)
A simple and practical method for the synthesis of substituted oxazoles has been developed using readily available α-bromoketones and benzylamines by visible-light photocatalysis at room temperature. The process, which requires 1 mol % of [Ru(bpy)3]Cl2 photocatalyst with K3PO4 and CCl3Br
Jun Chen et al.
Chemical communications (Cambridge, England), 54(50), 6780-6783 (2018-02-06)
A visible light-driven photocatalytic generation of sulfonamidyl radicals, and application to intramolecular alkene hydroamination, has been accomplished, providing a mild and efficient approach to various functionalized isoxazolidines. The success of this protocol is based on the strategy of oxidative deprotonation
Adam Noble et al.
Angewandte Chemie (International ed. in English), 57(8), 2155-2159 (2018-01-10)
The synthesis of alkyl boronic esters by direct decarboxylative radical addition of carboxylic acids to vinyl boronic esters is described. The reaction proceeds under mild photoredox catalysis and involves an unprecedented single-electron reduction of an α-boryl radical intermediate to the

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 risposta

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Utile?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 risposta

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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