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754730

Sigma-Aldrich

Tris(2,2′-bipyridine)ruthenium(II) hexafluorophosphate

97%

Sinonimo/i:

Ru(bpy)3(PF6)2, Ruthenium-tris(2,2′-bipyridyl) dihexafluorophosphate

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About This Item

Formula empirica (notazione di Hill):
C30H24F12N6P2Ru
Numero CAS:
60804-74-2
Peso molecolare:
859.55
Numero MDL:
MFCD11042502
Codice UNSPSC:
12352103
ID PubChem:
329766452
NACRES:
NA.23

Saggio

97%

Forma fisica

solid

Impiego in reazioni chimiche

core: ruthenium
reaction type: Photocatalysis
reagent type: catalyst

Impurezze

(Material is not fluorescence active.)

Punto di fusione

>300 °C

Attivazione fotocatalizzatore

425 nm

Assorbimento

13,400 at 456 nm
80,000 at 291 nm

Stringa SMILE

[Ru++].F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.c1ccc(nc1)-c2ccccn2.c3ccc(nc3)-c4ccccn4.c5ccc(nc5)-c6ccccn6

InChI

1S/3C10H8N2.2F6P.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2*1-7(2,3,4,5)6;/h3*1-8H;;;/q;;;2*-1;+2
KLDYQWXVZLHTKT-UHFFFAOYSA-N

Categorie correlate

Descrizione generale

Tris(2,2′-bipyridine)ruthenium(II) hexafluorophosphate (Ru(bpy)3(PF6)2) is a conducting polymer that is majorly used as an active layer in electrochemical devices. It facilitates the formation of highly efficient and low voltage devices. It shows an external quantum efficiency of 0.35 and 400 cd/m2 at 3V.

Applicazioni

Ru(bpy)3(PF6)2 may be used as a conjugating polymer in the development of light emitting electrochemical cell based devices such as light emitting diodes (LEDs). It is also used as a high-efficiency triplet emitter for OLED/Sensor research.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Prodotti correlati

N° Catalogo
Descrizione
Determinazione del prezzo

903426

Ru(p-CF3-bpy)3 (BF4)2, ≥95%

904767

[Ru(phen)3]Cl2, ≥95%

904945

[Ru(dmbpy)3](PF6)2, ≥95%

904953

[Ru(dtbbpy)3](PF6)2, ≥95%

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Certificati d'analisi (COA)

Cerca il Certificati d'analisi (COA) digitando il numero di lotto/batch corrispondente. I numeri di lotto o di batch sono stampati sull'etichetta dei prodotti dopo la parola ‘Lotto’ o ‘Batch’.

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Thin-film solid-state electroluminescent devices based on tris (2, 2 `-bipyridine) ruthenium (II) complexes
Buda, M
Journal of the American Chemical Society, 124(21), 6090-6098 (2002)
Single layer light-emitting devices with high efficiency and long lifetime based on tris (2, 2? bipyridyl) ruthenium (II) hexafluorophosphate
Rudmann H and Rubner MF
Journal of Applied Physics, 90(9), 4338-4345 (2001)
Silvia Voci et al.
Analytical and bioanalytical chemistry, 412(17), 4067-4075 (2020-04-29)
Nanofluidic electrochemical devices confine the volume of chemical reactions to femtoliters. When employed for light generation by electrochemiluminescence (ECL), nanofluidic confinement yields enhanced intensity and robust luminescence. Here, we investigate different ECL pathways, namely coreactant and annihilation ECL in a
Valentina Leandri et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 20(4), 618-626 (2019-01-10)
The excited state dynamics of Tris(2,2'-bipyridine)ruthenium(II) hexafluorophosphate, [Ru(bpy)3 (PF6 )2 ], was investigated on the surface of bare and sensitized TiO2 and ZrO2 films. The organic dyes LEG4 and MKA253 were selected as sensitizers. A Stern-Volmer plot of LEG4-sensitized TiO2
Direct measurement of the electric-field distribution in a light-emitting electrochemical cell
Slinker JD, et al.
Testing, 6(11), 894-894 (2007)
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