206911

Aluminum chloride

reagent grade, 98%

• Lineáris képlet: AlCl₃
• CAS-szám: 7446-70-0
• Molekulatömeg: 133.34
• EC-szám: 231-208-1
• MDL-szám: MFCD00003422
• UNSPSC kód: 12352302
• eCl@ss: 38120507
• PubChem Substance ID: 329752018
• NACRES: NA.21

Tulajdonságok

• grade: reagent grade
• Minőségi szint: 100
• gőznyomás: 1 mmHg ( 100 °C)
• Teszt: 98%
• form: powder or chunks
• reakcióalkalmasság: reagent type: catalyst; core: aluminum
• pH: 2.4 (20 °C, 100 g/L)
• mp: 190 °C (lit.)
• SMILES string: Cl[Al](Cl)Cl
• InChI: 1S/Al.3ClH/h;3*1H/q+3;;;/p-3
• Nemzetközi kémiai azonosító kulcs: VSCWAEJMTAWNJL-UHFFFAOYSA-K

Leírás

Általános leírás

Aluminum chloride participates in the amination of exo-2-chloronorbornane to afford 2-azabicyclo[3.2.1]octane, small amounts of the 3-isomer and exo-2-aminonorbornane. It has been reported to promote the Friedel-Crafts acylation of 4-tert-butylbenzoyl chloride with mesitylene.

Alkalmazás

Aluminum chloride has been employed for the estimation of total contents of flavonoids in a freeze-dried extract isolated from Issopus officinalis. It has been employed for the synthesis of the following compounds:

• 3′-methyl-5′,6′,7′,7a′-tetrahydro-4′H-spiro(cyclohexane-1,1′-isobenzofuran)
• trans-methyl 2-(cyclohex-1-enyl)cyclohexyl ketone
• 1,1,3-trimethyl-1,4,5,6,7,7a-hexahydroisobenzofuran
• 1-((2R*,4aS*,8aR*)-2-methyldecahydronaphthalen-4ayl)ethanone

Aluminum chloride may be used as catalyst for the Friedel-Crafts polymerizations of 4-(trifluoromethoxy)benzyl bromide. It may be employed as catalyst for Fries rearrangement of phenyl isobutyrate at 140°C to afford a mixture of 2-hydroxy- and 4-hydroxy-isobutyrophenone.
It may be used to catalyze:

• Degradation of polystyrene to benzene.
• Carbonization of polycyclic aromatic hydrocarbons.
• Colorimetric microassay of hydroperoxides.

Tulajdonságok és előnyök

The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties. Aluminum nitride can be synthesized from the elemnts with AlCl₃ added to help facilitate crystallization.

Biztonsági adatok

• Piktogramok: GHS05
• Figyelmeztetés: Danger
• Figyelmeztető mondatok: H314
• Óvintézkedésre vonatkozó mondatok: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Veszélyességi osztályok: Eye Dam. 1 - Skin Corr. 1B
• Egyéb veszélyek: EUH014,EUH071
• Tárolási osztály kódja: 8A - Combustible corrosive hazardous materials
• WGK: WGK 1
• Lobbanási pont (F): Not applicable
• Lobbanási pont (C): Not applicable