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176427

Sigma-Aldrich

Silver p-toluenesulfonate

≥99%

Synonyma:

p-Toluenesulfonic acid silver salt, Silver tosylate

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About This Item

Lineární vzorec:
CH3C6H4SO3Ag
Číslo CAS:
16836-95-6
Molekulová hmotnost:
279.06
Beilstein/REAXYS Number:
3598937
EC Number:
240-859-0
MDL number:
MFCD00007511
UNSPSC Code:
12352302
PubChem Substance ID:
24850577
NACRES:
NA.23
assay:
≥99%
form:
powder

Quality Level

100

assay

≥99%

form

powder

reaction suitability

reagent type: catalyst
core: silver

SMILES string

[Ag+].Cc1ccc(cc1)S([O-])(=O)=O

InChI

1S/C7H8O3S.Ag/c1-6-2-4-7(5-3-6)11(8,9)10;/h2-5H,1H3,(H,8,9,10);/q;+1/p-1

InChI key

JUDUFOKGIZUSFP-UHFFFAOYSA-M

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Application

Converts alkyl halides to tosylates, and benzyl selenyl chlorides into their corresponding selenyl tosylates.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Vyberte jednu z posledních verzí:

Osvědčení o analýze (COA)

Lot/Batch Number
MKCL3828
MKBZ5403V
MKBS5453V
MKBJ0656V
82396KJV

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Sigma-Aldrich

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Sigma-Aldrich

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Sigma-Aldrich

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The Journal of Organic Chemistry, 56, 2781-2781 (1991)
Iliyan Ivanov et al.
Molecules (Basel, Switzerland), 16(8), 7019-7042 (2011-08-19)
A series of different 1-monosubstituted and 1,1-disubstituted 1,2,3,4-tetrahydro-isoquinolines was synthesized in high yields from different ketoamides. We have developed a convenient method for the synthesis of disubstituted derivatives by interaction of ketoamides with organomagnesium compounds, followed by cyclization in the
Chika Taniguchi et al.
International journal of pharmaceutics, 434(1-2), 148-154 (2012-05-31)
This study was undertaken to develop new dipyridamole (DP) formulations with acidic microenvironmental pH-modifiers for improving dissolution and absorption under hypochlorhydric conditions. Dipyridamole granules (DPG) with ten acidic pH-modifiers were prepared with conventional wet granulation, and their manufacturability, stability and
Ljupčo Pejov et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 79(1), 27-34 (2011-03-23)
The 1:1 p-toluenesulfonic acid-water complex, p-toluenesulfonic acid itself and the p-toluenesulfonate anion were studied at HF and B3LYP/6-31+G(d,p) levels of theory. Full geometry optimizations of the aforementioned species reveal non-existence of ionic minima on the explored 1:1 p-toluenesulfonic acid-water complex
Francis Gosselin et al.
The Journal of organic chemistry, 75(12), 4154-4160 (2010-05-22)
Practical, chromatography-free syntheses of 5-lipoxygenase inhibitor MK-0633 p-toluenesulfonate (1) are described. The first route used an asymmetric zincate addition to ethyl 2,2,2-trifluoropyruvate followed by 1,3,4-oxadiazole formation and reductive amination as key steps. An improved second route features an inexpensive diastereomeric
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