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Merck

244759

Sigma-Aldrich

Titan(IV)-ethoxid

technical grade

Synonym(e):

Tetraethyl-orthotitanat, Tetraethyltitanat

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50 G
CHF 101.00
250 G
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About This Item

Lineare Formel:
Ti(OC2H5)4
CAS-Nummer:
Molekulargewicht:
228.11
Beilstein:
3678992
MDL-Nummer:
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.23

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Qualität

technical grade

Qualitätsniveau

Form

liquid

Zusammensetzung

Ti, 19.0-21.0% gravimetric

Eignung der Reaktion

core: titanium
reagent type: catalyst

Verunreinigungen

~20% Tetraisopropyl orthotitanate

Brechungsindex

n20/D 1.505 (lit.)

bp

150-152 °C/10 mmHg (lit.)

Dichte

1.088 g/mL at 25 °C (lit.)

SMILES String

CCO[Ti](OCC)(OCC)OCC

InChI

1S/4C2H5O.Ti/c4*1-2-3;/h4*2H2,1H3;/q4*-1;+4

InChIKey

JMXKSZRRTHPKDL-UHFFFAOYSA-N

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Anwendung

Titanethoxid wird häufig als Vorläufer bei der Synthese von Ti4+-Ionen[1]-Titannanoteilchen mit verschiedenen Verfahren eingesetzt:
  • bei der Sol-Gel-Synthese von freistehenden ferroelektrischen Bleititanatzirkonat-Nanoteilchen[2]
  • kugelförmige Titankerne, hergestellt entweder durch Hydrolyse von Ti(IV)-Ethoxidtropfen in Kontakt mit Wasserdampf[3] oder
  • durch Präadsorption der Titanalkoxide auf die Tonmineralplättchen und ihre anschließende Hydrolyse und Kalzinierung.[4]

Piktogramme

FlameExclamation mark

Signalwort

Warning

H-Sätze

Gefahreneinstufungen

Eye Irrit. 2 - Flam. Liq. 3

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 3

Flammpunkt (°F)

107.6 °F - closed cup

Flammpunkt (°C)

42 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Thin Solid Films, 453, 518-521 (2004)
Preparation of uniform spherical titania particles coated with polyurea by the aerosol technique.
Mayville FC, et al.
Journal of Colloid and Interface Science, 120(1), 135-139 (1987)
Preparation and characterization of clay mineral intercalated titanium dioxide nanoparticles
Mogyorosi K, et al.
Langmuir, 19(7), 2938-2946 (2003)
Improved synthesis of enantiopure sulfinimines (thiooxime s-oxides) from p-toluenesulfinamide and aldehydes and ketones
Davis FA, et al.
The Journal of Organic Chemistry, 64(4), 1403-1406 (1999)
Johan Karlsson et al.
International journal of nanomedicine, 10, 4425-4436 (2015-07-18)
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Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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