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240761

Sigma-Aldrich

1-Hexen

≥99%

Synonym(e):

1-n-Hexene

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About This Item

Lineare Formel:
CH3(CH2)3CH=CH2
CAS-Nummer:
592-41-6
Molekulargewicht:
84.16
Beilstein:
1209240
EG-Nummer:
209-753-1
MDL-Nummer:
MFCD00009505
UNSPSC-Code:
12352100
PubChem Substanz-ID:
24854435
NACRES:
NA.22

Dampfdichte

3 (vs air)

Dampfdruck

155 mmHg ( 21.1 °C)

Assay

≥99%

Form

liquid

Selbstzündungstemp.

487 °F

Brechungsindex

n20/D 1.388 (lit.)

bp

60-66 °C (lit.)

Dichte

0.678 g/mL at 25 °C (lit.)

SMILES String

CCCCC=C

InChI

1S/C6H12/c1-3-5-6-4-2/h3H,1,4-6H2,2H3

InChIKey

LIKMAJRDDDTEIG-UHFFFAOYSA-N

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Allgemeine Beschreibung

The kinetics of polymerization of 1-hexene was studied using a family of five zirconium amine bis-phenolate catalysts. Polymerization reaction of 1-hexene catalyzed by a series of hafnium complexes was studied.

Anwendung

  • 1-Hexene in High Molecular Weight Polymer Synthesis: The synthesis of high molecular weight copolymers from 1-hexene and methyl acrylate using Lewis acid catalysts showcased advanced applications in materials science, specifically in developing durable and versatile polymer materials (Wan et al., 2024).
  • 1-Hexene′s Role in Proton-Exchange Membrane Enhancement: Utilizing 1-hexene in the structural characterization and enhancement of physicochemical properties of functionally porous proton-exchange membranes highlights its critical role in improving energy efficiency and performance in fuel cell technologies (Ponomar et al., 2024).

Piktogramme

FlameHealth hazard
GHS02,GHS08

Signalwort

Danger

H-Sätze

H225,H304

Gefahreneinstufungen

Asp. Tox. 1 - Flam. Liq. 2

Zusätzliche Gefahrenhinweise

EUH066

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 2

Flammpunkt (°F)

-13.0 °F - closed cup

Flammpunkt (°C)

-25.0 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Analysenzertifikate (COA)

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Sigma-Aldrich

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1-Octen analytical standard

Supelco

74900

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trans-3-Hexen ≥99%

Sigma-Aldrich

447153

trans-3-Hexen

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Sigma-Aldrich

128570

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Sigma-Aldrich

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Sigma-Aldrich

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Cyclohexen inhibitor-free, ReagentPlus®, 99%

Sigma-Aldrich

125431

Cyclohexen

Takahiro Yasumoto et al.
Dalton transactions (Cambridge, England : 2003), 42(25), 9120-9128 (2012-12-14)
Non-bridged half-metallocene dimethyl complexes of group 4 metals 2a-4a with an N-4-methoxyphenyl(iminomethyl)pyrrolyl ligand 1a were synthesized and characterized by NMR spectroscopy and X-ray analysis. Upon activation with [Ph3C][B(C6F5)4], these complexes became active catalysts for the polymerization of 1-hexene. A series
D Keith Steelman et al.
Journal of the American Chemical Society, 135(16), 6280-6288 (2013-03-23)
The kinetics of 1-hexene polymerization using a family of five zirconium amine bis-phenolate catalysts, Zr[tBu-ON(X)O]Bn2 (where X = THF (1), pyridine (2), NMe2 (3), furan (4), and SMe (5)), has been investigated to uncover the mechanistic effect of varying the
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The stereochemistry, kinetics, and mechanism of olefin polymerization catalyzed by a set of zirconium-based metallocenes was studied by NMR using dissolution dynamic nuclear polarization (DNP). Hyperpolarized 1-hexene was polymerized in situ with a C2 symmetric catalyst, [(EBI)ZrMe][B(C6F5)4] (EBI = rac-(C2H4(1-indenyl)2))
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