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Sigma-Aldrich

Sodium persulfate

reagent grade, ≥98%

Sinônimo(s):

Sodium peroxodisulfate

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About This Item

Fórmula linear:
Na2S2O8
Número CAS:
7775-27-1
Peso molecular:
238.10
Número CE:
231-892-1
Número MDL:
MFCD00003501
Código UNSPSC:
12352302
ID de substância PubChem:
329752185
NACRES:
NA.21
Preço e disponibilidade não estão disponíveis no momento.

grau

reagent grade

Nível de qualidade

200

Ensaio

≥98%

Formulário

powder, crystals or granules

adequação da reação

reagent type: oxidant

cadeia de caracteres SMILES

[Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O

InChI

1S/2Na.H2O8S2/c;;1-9(2,3)7-8-10(4,5)6/h;;(H,1,2,3)(H,4,5,6)/q2*+1;/p-2

chave InChI

CHQMHPLRPQMAMX-UHFFFAOYSA-L

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Descrição geral

Sodium persulfate, also known as Sodium peroxodisulfate is an inorganic compound and is a water-soluble strong oxidizing agent, that is stable and easy to handle. It is commonly used as an oxidant in organic synthesis reactions such as transition-metal-catalyzed or metal-free reactions. Additionally, it is used as a polymerization initiator and in the synthesis of sulfate radical anions through heat-activated decomposition. [1]

Aplicação

Sodium persulfate can be used as an oxidant:
  • For the radical cyclization cascade reaction of 2-alkynylbenzonitriles and sodium arylsulfinates to synthesize sulfonated indenones.
  • In the silica-supported aluminum chloride-catalyzed Baeyer-Villiger oxidation of cyclic and acyclic ketones to lactones or esters.
It can also be used as an initiator for the polymerization of styrene to synthesize polystyrene.

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 4 Oral - Ox. Sol. 3 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

5.1B - Oxidizing hazardous materials

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

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Certificados de análise (COA)

Lot/Batch Number
BCCM7877
BCCM0882
BCCK6186
BCCL1229
BCCG9836

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PCE oxidation by sodium persulfate in the presence of solids
Jed C, et al.
Environmental Science & Technology, 44, 9445-9450 (2010)
Esther Eljarrat-Binstock et al.
Investigative ophthalmology & visual science, 45(8), 2543-2548 (2004-07-28)
To assess the corneal iontophoretic delivery of gentamicin by drug-loaded hydrogel probe, and to determine the resultant ocular disposition and elimination of the drug from the cornea and anterior chamber. Corneal iontophoresis of gentamicin sulfate was studied in healthy white
Chia-Hsien Yen et al.
Journal of hazardous materials, 186(2-3), 2097-2102 (2011-01-25)
In this study, batch experiments were conducted to evaluate the feasibility of petroleum-hydrocarbon contaminated soil remediation using persulfate oxidation. Various controlling factors including different persulfate and ferrous ion concentrations, different oxidants (persulfate, hydrogen peroxide, and permanganate), and different contaminants (diesel
José Fenoll et al.
Journal of hazardous materials, 244-245, 370-379 (2012-12-29)
The photocatalytic degradation of sixteen substituted phenylurea herbicides (PUHs) in pure water has been studied using zinc oxide (ZnO) and titanium dioxide (TiO(2)) as photocatalyst under artificial light irradiation. Photocatalytic experiments showed that the addition of these chalcogenide oxides in
Ya-Ting Lin et al.
Chemosphere, 82(8), 1168-1172 (2011-01-12)
Using ultraviolet photolytic persulfate activation to produce two sulfate radicals (SO(4)(-)) exhibits a potential for destroying organic contaminants in wastewater treatment applications. This study investigated both the feasibility of using a UV/SPS (sodium persulfate) process to treat phenol in aqueous
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1–2 of 2 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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