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C102504

Sigma-Aldrich

Cyclohexene oxide

98%

Sinônimo(s):

1,2-Epoxycyclohexane, 7-Oxabicyclo[4.1.0]heptane

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About This Item

Fórmula empírica (Notação de Hill):
C6H10O
Número CAS:
286-20-4
Peso molecular:
98.14
Beilstein:
383568
Número CE:
206-007-7
Número MDL:
MFCD00005162
Código UNSPSC:
12162002
ID de substância PubChem:
24892306
NACRES:
NA.23

Nível de qualidade

100

Ensaio

98%

Formulário

liquid

temperatura de autoignição

703 °F

Lim. expl.

12.36 %

índice de refração

n20/D 1.452 (lit.)

p.e.

129-130 °C (lit.)

densidade

0.97 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

C1CCC2OC2C1

InChI

1S/C6H10O/c1-2-4-6-5(3-1)7-6/h5-6H,1-4H2

chave InChI

ZWAJLVLEBYIOTI-UHFFFAOYSA-N

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Categorias relacionadas

Aplicação

  • Polymeric carbon nitride with internal np homojunctions for efficient photocatalytic CO2 reduction coupled with cyclohexene oxidation: This study focuses on the use of cyclohexene oxide in the context of photocatalytic CO2 reduction, highlighting the application of polymeric carbon nitride as a catalyst. The process shows how cyclohexene oxide can be efficiently converted in a coupled reaction that also addresses environmental concerns through CO2 reduction (W Zhen et al., 2021).

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Skin Corr. 1B

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 1

Equipamento de proteção individual

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Escolha uma das versões mais recentes:

Certificados de análise (COA)

Lot/Batch Number
MKCW5349
MKCT8260
MKCV4121
MKCP5868
MKCM7818

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2-Cyclohexen-1-ol 95%

Sigma-Aldrich

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Cyclohexene contains 100 ppm BHT as inhibitor, ≥99.0%

Sigma-Aldrich

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1,2-Epoxyoctane 96%

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Bismuth(III) nitrate pentahydrate ACS reagent, ≥98.0%

Sigma-Aldrich

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Bismuth(III) nitrate pentahydrate

Donald J Darensbourg et al.
Journal of the American Chemical Society, 127(40), 14026-14038 (2005-10-06)
The mechanism of the copolymerization of cyclohexene oxide and carbon dioxide to afford poly(cyclohexylene)carbonate catalyzed by (salen)CrN3 (H2salen = N,N,'-bis(3,5-di-tert-butylsalicylidene)-1,2-ethylene-diimine) in the presence of a broad range of cocatalysts has been studied. We have previously established the rate of copolymer
Kathila S Rajapaksa et al.
Toxicological sciences : an official journal of the Society of Toxicology, 96(2), 327-334 (2007-01-06)
Ovarian follicle disruption in mice caused by 7,12-dimethylbenz[a]anthracene (DMBA) is attributed to its bioactivation by CYP1B1 to a 3,4-epoxide which is then hydrolyzed to form a 3,4-diol by microsomal epoxide hydrolase (mEH). Further epoxidation by CYP1A1 or 1B1 forms the
Alternating copolymerization of epoxides and cyclic anhydrides: an improved route to aliphatic polyesters.
Ryan C Jeske et al.
Journal of the American Chemical Society, 129(37), 11330-11331 (2007-08-29)
Youli Xiao et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 11(12), 3668-3678 (2005-04-14)
The intramolecular dinuclear zinc complexes generated in situ from the reaction of multidentate semi-azacrown ether ligands with Et(2)Zn, followed by treatment with an alcohol additive, were found to promote the copolymerization of CO(2) and cyclohexene oxide (CHO) with completely alternating
M Amedjkouh et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 7(20), 4368-4377 (2001-11-07)
Improved stereoselectivity has been obtained by using 2-lithium-1-methylimidazole, 2, as a replacement for lithium diisopropylamide (LDA) as a bulk base in catalytic deprotonations. The chiral lithium amide 6 of (1R,2S)-N-methyl-1-phenyl-2-pyrrolidinylpropanamine, 5, has been found to deprotonate cyclohexene oxide 3 in
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