747912

Boxed reaction: Sonogashira Reaction in Lipshutz Surfactant

• Código UNSPSC: 12161600
• NACRES: NA.22

Propriedades

• adequação da reação: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• características do produto alternativo mais ecológico: Waste Prevention; Designing Safer Chemicals; Design for Energy Efficiency; Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• categoria alternativa mais ecológica: Aligned,
• temperatura de armazenamento: −20°C

Descrição

Descrição geral

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Aplicação

This kit contains the reagents, catalyst, and solvent required to perform a Sonogashira reaction in TPGS-750-M, a surfactant developed by the Lipshutz group as a greener alternative to organic solvents. This technology allows common metal-catalyzed reactions to be run under aqueous conditions, considerably reducing solvent waste. The components are pre-weighed in the appropriate amounts for a 1 mmol scale reaction.

Please refer to the attached Protocol for details.

Componentes do kit também disponíveis separadamente

• 225657 Bis(acetonitrile)dichloropalladium(II), 99% 5 mg
• 638064 XPhos, 98% 12 mg
• 763918 DL-α-Tocopherol methoxypolyethylene glycol succinate solution, 5 wt. % in H₂O 2 mL
• T0886 Triethylamine, ≥99% .28 mL

Informações de segurança

• Pictogramas: GHS02,GHS06,GHS05
• Palavra indicadora: Danger
• Frases de perigo: H225,H301 + H311 + H331,H314,H335
• Declarações de precaução: P210 - P233 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Classificações de perigo: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3
• Órgãos-alvo: Respiratory system
• Código de classe de armazenamento: 3 - Flammable liquids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): 5.0 °F
• Ponto de fulgor (°C): -15 °C