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Sigma-Aldrich

Nickel(II) chloride ethylene glycol dimethyl ether complex

98%

Sinônimo(s):

Dichloro(dimethoxyethane)nickel, NiCl2 glyme

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About This Item

Fórmula linear:
NiCl2:CH3OCH2CH2OCH3
Número CAS:
29046-78-4
Peso molecular:
219.72
Número MDL:
MFCD00013481
Código UNSPSC:
12161600
ID de substância PubChem:
329761848
NACRES:
NA.22

Ensaio

98%

forma

powder

adequação da reação

core: nickel
reagent type: catalyst

pf

>300 °C

cadeia de caracteres SMILES

Cl[Ni]Cl.COCCOC

InChI

1S/C4H10O2.2ClH.Ni/c1-5-3-4-6-2;;;/h3-4H2,1-2H3;2*1H;/q;;;+2/p-2

chave InChI

OCMNCWNTDDVHFK-UHFFFAOYSA-L

Categorias relacionadas

Aplicação

Nickel(II) chloride ethylene glycol dimethyl ether complex can be used:
  • As a catalyst for the borylation of racemic benzylic chloride to synthesize enantioenriched benzylic boronic esters.
  • As a promoter for the trifluoromethylation of alkyl iodides to synthesize broad range of alkyl-CF3 compounds.
  • For the synthesis of nickel bis(benzimidazol-2-ylidene) pincer complexes which can be used for electrocatalytic reduction of CO2 to CO.
  • As a Lewis acid catalyst for C-acylation β-ketoesters through photoactivation by visible light.

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Water-react 2

Código de classe de armazenamento

4.3 - Hazardous materials which set free flammable gases upon contact with water

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificados de análise (COA)

Busque Certificados de análise (COA) digitando o Número do Lote do produto. Os números de lote e remessa podem ser encontrados no rótulo de um produto após a palavra “Lot” ou “Batch”.

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Nickel-based Catalysts

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