437727

Tetrahydrofuran-d₈

≥99.5 atom % D, contains 0.03 % (v/v) TMS

• Sinônimo(s): THF-d₈, Deuterated tetrahydrofuran, Octadeuterotetrahydrofuran
• Fórmula empírica (Notação de Hill): C₄D₈O
• Número CAS: 1693-74-9
• Peso molecular: 80.16
• Beilstein: 111854
• Número MDL: MFCD00044238
• Código UNSPSC: 12142201
• ID de substância PubChem: 24867392
• NACRES: NA.21

Propriedades

• pureza isotópica: ≥99.5 atom % D
• Nível de qualidade: 200
• Ensaio: ≥99% (CP)
• Formulário: liquid
• contém: 0.03 % (v/v) TMS
• técnica(s): NMR: suitable
• Impurezas: ≤0.03% water; water
• índice de refração: n20/D 1.403 (lit.)
• p.e.: 65-66 °C (lit.)
• pf: −106 °C (lit.)
• densidade: 0.985 g/mL at 25 °C (lit.)
• alteração de massa: M+8
• temperatura de armazenamento: 2-8°C
• cadeia de caracteres SMILES: [2H]C1([2H])OC([2H])([2H])C([2H])([2H])C1([2H])[2H]
• InChI: 1S/C4H8O/c1-2-4-5-3-1/h1-4H2/i1D2,2D2,3D2,4D2
• chave InChI: WYURNTSHIVDZCO-SVYQBANQSA-N

Descrição

Descrição geral

Tetrahydrofuran-d₈ (THF-d₈, TDF) is a deuterated NMR solvent containing 0.03% (v/v) TMS (tetramethylsilane). It is useful in NMR-based research and analyses. ¹H NMR line shape analysis of the exchange rates of proton between methanol and acetic acid dissolved in THF-d₈ was reported.[1] It participates as a solvent in the synthesis of deuteriotris[bis(trimethylsilyl)amido]thorium and deuteriotris[bis(trimethylsiiyl)amido]uranium.[2] Dynamic NMR spectroscopic study of ¹⁵N,¹⁵N′-dipentadeuterophenylformamidine (DPFA) has been studied in THF-d₈.[3]

Aplicação

• Experimental and Theoretical Study of CO2 Insertion into Ruthenium Hydride Complexes.: This research provides insights into the mechanistic pathways for CO2 reactivity with ruthenium hydride complexes, potentially relevant for catalytic applications including transformations involving Tetrahydrofuran-d₈ (Ramakrishnan et al., 2016).



• Syntheses, structures, and NMR chemical shifts of a family of trimethyltin alkoxide, amide, halide and cyclopentadienyl compounds.: Details the synthesis and structural characterization of trimethyltin compounds, useful for understanding the coordination chemistry that may involve Tetrahydrofuran-d₈ as a solvent or structural analogue (Lichtscheidl et al., 2015).


• NMR studies of coupled low- and high-barrier hydrogen bonds in pyridoxal-5′-phosphate model systems in polar solution.: Discusses the application of NMR spectroscopy in studying hydrogen bonding interactions, where Tetrahydrofuran-d₈ could be utilized as a deuterated solvent for enhanced spectral clarity (Sharif et al., 2007).



• Stable hydrocarbon diradical, an analogue of trimethylenemethane.: Investigates stable hydrocarbon diradicals, where Tetrahydrofuran-d₈ may be used as part of the experimental setup to stabilize reactive intermediates or as a solvent to study radical stability (Rajca et al., 2005).

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Informações de segurança

• Pictogramas: GHS02,GHS08,GHS07
• Palavra indicadora: Danger
• Frases de perigo: H225,H302,H319,H335,H336,H351
• Declarações de precaução: P202 - P210 - P233 - P301 + P312 - P305 + P351 + P338 - P308 + P313
• Classificações de perigo: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• Órgãos-alvo: Central nervous system, Respiratory system
• Perigos de suplementos: EUH019
• Código de classe de armazenamento: 3 - Flammable liquids
• Classe de risco de água (WGK): WGK 1
• Ponto de fulgor (°F): 1.4 °F - closed cup
• Ponto de fulgor (°C): -17 °C - closed cup