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444863

Sigma-Aldrich

Acetone-d6

99.9 atom % D

Sinônimo(s):

Hexadeuteroacetone

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About This Item

Fórmula linear:
CD3COCD3
Número CAS:
Peso molecular:
64.12
Beilstein:
1702935
Número CE:
Número MDL:
Código UNSPSC:
12142201
ID de substância PubChem:
NACRES:
NA.11
Preço e disponibilidade não estão disponíveis no momento.

densidade de vapor

2 (vs air)

Nível de qualidade

pressão de vapor

14.39 psi ( 55 °C)
184 mmHg ( 20 °C)
3.67 psi ( 20 °C)

pureza isotópica

99.9 atom % D

Ensaio

≥99% (CP)

Formulário

liquid

Lim. expl.

13.2 %

embalagem

Sure/Seal of 100 mL
ampule of 0.5 mL, 0.6 mL, 10 mL
glass bottle of 10, 25, 50 mL

IVD

for in vitro diagnostic use

técnica(s)

GC/MS: suitable
NMR: suitable

Impurezas

≤0.0500% water
water

índice de refração

n20/D 1.355 (lit.)

p.e.

55.5 °C (lit.)

pf

−93.8 °C (lit.)

densidade

0.872 g/mL at 25 °C (lit.)

alteração de massa

M+6

cadeia de caracteres SMILES

[2H]C([2H])([2H])C(=O)C([2H])([2H])[2H]

InChI

1S/C3H6O/c1-3(2)4/h1-2H3/i1D3,2D3

chave InChI

CSCPPACGZOOCGX-WFGJKAKNSA-N

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Descrição geral

Acetone-d6 is a deuterated NMR solvent useful in NMR-based research and analyses. Its Infrared and Raman spectra have been analyzed.[1] Pyrolysis and photolysis of acetone-d6 and methane mixtures have been investigated as a function of temperature.[2] It has been reported to be prepared by reacting heavy water with propyne-d4 in the presence of mercury catalyst.[3]

Aplicação

Acetone-d6 may be used as an internal standard to detect aldehydes and acetone in water by headspace-solid-phase microextraction and gas chromatography-mass spectrometry.[4]

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Informações legais

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Pictogramas

FlameExclamation mark

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

Órgãos-alvo

Central nervous system

Perigos de suplementos

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

-2.2 °F - closed cup

Ponto de fulgor (°C)

-19 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves


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Certificados de análise (COA)

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Hyun-Ji Kim et al.
Journal of separation science, 34(6), 693-699 (2011-02-15)
We describe a simple and automatic method to determine nine aldehydes and acetone simultaneously in water. This method is based on derivatization with 2,2,2-trifluoroethylhydrazine (TFEH) and consecutive headspace-solid-phase microextraction and gas chromatography-mass spectrometry. Acetone-d(6) was used as the internal standard.
The Pyrolysis and Photolysis of Acetone-d6 in the Presence of Methane.
McNesby JR and Gordon AS.
Journal of the American Chemical Society, 76(16), 4196-4198 (1954)
Vibrational spectra and assignment of acetone, ααα acetone-d3 and acetone-d6.
Dellepiane G and Overend J.
Spectrochimica Acta Part A: Molecular Spectroscopy, 22(4), 593-614 (1966)
Neue Synthese von Aceton-d6.
Hunziker H, et al.
Helvetica Chimica Acta, 45(1), 59-62 (1962)
Fujun Li et al.
Nature communications, 6, 7843-7843 (2015-07-25)
Lithium-oxygen cells have attracted extensive interests due to their high theoretical energy densities. The main challenges are the low round-trip efficiency and cycling instability over long time. However, even in the state-of-the-art lithium-oxygen cells the charge potentials are as high

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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