About This Item
Fórmula linear:
C6H5CH2OC6H5
Número CAS:
Peso molecular:
184.23
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22
Produtos recomendados
Ensaio
98%
p.e.
286-287 °C (lit.)
pf
39-41 °C (lit.)
grupo funcional
phenoxy
phenyl
cadeia de caracteres SMILES
C(Oc1ccccc1)c2ccccc2
InChI
1S/C13H12O/c1-3-7-12(8-4-1)11-14-13-9-5-2-6-10-13/h1-10H,11H2
chave InChI
BOTNYLSAWDQNEX-UHFFFAOYSA-N
Descrição geral
Benzyl phenyl ether is a reactive organic oxygenate, containing ether as functional group, present in subbituminous and bituminous coals.[1] It reacts with aluminium bromide in chlorobenzene solution to afford a mixture of phenol, o-benzyl phenol and dichlorodiphenylmethane.[2] It is a useful as model compound in catalytic chemistry to represent the a-O4 ether bond in lignin and coal. It contains a weak ether bond of 234kJ/mol and belongs to the most thermo-labile compounds in lignin and low rank coal.[3] Influence of alkali carbonates, common additives in biomass conversion, on the reaction pathways of BPE in superheated water has been reported.[3] Cesium-exchanged heteropolyacid catalyzed decomposition of benzyl phenyl ether to aromatics has been investigated.[4] Photo-Claisen rearrangements of benzyl phenyl ether was investigated in cation-exchanged Y zeolites and polyethylenes of differing crystallinities.[5]
Palavra indicadora
Warning
Frases de perigo
Declarações de precaução
Classificações de perigo
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Órgãos-alvo
Respiratory system
Código de classe de armazenamento
11 - Combustible Solids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
235.4 °F - closed cup
Ponto de fulgor (°C)
113 °C - closed cup
Equipamento de proteção individual
dust mask type N95 (US), Eyeshields, Gloves
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Influence of alkali carbonates on benzyl phenyl ether cleavage pathways in superheated water.
Roberts V, et al.
Applied Catalysis. B, Environmental, 95(1), 71-77 (2010)
Understanding the influence of active (zeolite) and passive (polyethylene) reaction cages on photo-Claisen rearrangements of aryl benzyl ethers.
Gu W, et al.
Langmuir, 16(17), 6977-6981 (2000)
Hongliang Wang et al.
ChemSusChem, 11(15), 2562-2568 (2018-07-04)
Hydrodeoxygenation of biorefinery lignin-rich wastes to jet fuel hydrocarbons offers a significant opportunity for enhancing the overall operational efficiency, carbon conversion efficiency, economic viability, and sustainability of biofuels production. However, these wastes usually mainly contain lignin with sugars, furans, and
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Materials (Basel, Switzerland), 13(3) (2020-02-09)
Monometallic cerium layered double hydroxides (Ce-LDH) supports were successfully synthesized by a homogeneous alkalization route driven by hexamethylenetetramine (HMT). The formation of the Ce-LDH was confirmed and its structural and compositional properties studied by XRD, SEM, XPS, iodometric analyses and
Catalytic decomposition of benzyl phenyl ether to aromatics over cesium-exchanged heteropolyacid catalyst.
Park HW, et al.
Korean Journal of Chemical Engineering, 28(5), 1177-1180 (2011)
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