255025

Hexylmagnesium bromide solution

2.0 M in diethyl ether

• Sinônimo(s): 1-Hexylmagnesium bromide, Bromohexylmagnesium, n-hexylmagnesium bromide
• Fórmula linear: CH₃(CH₂)₅MgBr
• Número CAS: 3761-92-0
• Peso molecular: 189.38
• Beilstein: 3535624
• Número MDL: MFCD00000046
• Código UNSPSC: 12352103
• ID de substância PubChem: 24855279
• NACRES: NA.22

Propriedades

• adequação da reação: reaction type: Grignard Reaction
• concentração: 2.0 M in diethyl ether
• densidade: 0.965 g/mL at 25 °C
• cadeia de caracteres SMILES: CCCCCC[Mg]Br
• InChI: 1S/C6H13.BrH.Mg/c1-3-5-6-4-2;;/h1,3-6H2,2H3;1H;/q;;+1/p-1
• chave InChI: SFXUWNMDTWQSHE-UHFFFAOYSA-M

Descrição

Descrição geral

Hexylmagnesium bromide, also known as n-hexylmagnesium bromide, is a useful organomagnesium compound that is commonly used in organic synthesis. It is typically prepared by reacting magnesium turnings with 1-bromohexane in diethyl ether solvent.

Aplicação

Hexylmagnesium bromide solution can be used as a reagent in addition reactions. It can add to various electrophiles, such as carbonyl compounds, to form alcohols or carboxylic acids. These types of reactions are commonly used for the synthesis of pharmaceuticals, natural products, and other organic compounds. It is also used to reduce certain functional groups, such as ketones, esters, and nitriles, to form alcohols or amines.

Informações de segurança

• Pictogramas: GHS02,GHS05,GHS07
• Palavra indicadora: Danger
• Frases de perigo: H225,H260,H302,H314,H336
• Declarações de precaução: P210 - P231 + P232 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Classificações de perigo: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• Órgãos-alvo: Central nervous system
• Perigos de suplementos: EUH019
• Código de classe de armazenamento: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): -40.0 °F - closed cup
• Ponto de fulgor (°C): -40 °C - closed cup
• Equipamento de proteção individual: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter