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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
656984
Isopropylmagnesium chloride lithium chloride complex solution
1.3 M in THF
Sinônimo(s):
Turbo Grignard
About This Item
Produtos recomendados
adequação da reação
reaction type: Grignard Reaction
Nível de qualidade
100
200
concentração
1.3 M in THF
densidade
0.951 g/mL at 25 °C
cadeia de caracteres SMILES
[Li]Cl.CC(C)[Mg]Cl
InChI
1S/C3H7.2ClH.Li.Mg/c1-3-2;;;;/h3H,1-2H3;2*1H;;/q;;;2*+1/p-2
chave InChI
CWTUREABAILGIK-UHFFFAOYSA-L
Aplicação
Used for:
- Preparation of functionalized acyclic alkenyl magnesium reagents/preparation of 1,2-diketones
- Preparation of cyclic alkenyl and dienyl magnesium reagents
- Preparation of functionalized triazenes/preparation of carbazoles
- Regioselective functionalization of trisubstituted pyridines
- Electrophilic amination for preparation of amines
- Preparation of Grignards reagents in the presence of masked ketones and aldehydes (using readily deprotectable silylated cyanohydrins)
- Preparation of Benzylic Grignards via Sulfur-Magnesium exchange
- Functionalization via I-Mg Exchange of unprotected aromatic and heteroaromatic carboxylic acids
- Functionalization via I-Mg Exchange of unprotected imidazoles
- Pyridyne formation
- Functionalization of cyclopentene derivatives
- Preparation of 2,3-functionalized furans, benzofurans, and thiophenes
- Stereoselective synthesis of substituted cyclopropanes
Embalagem
Informações legais
Palavra indicadora
Danger
Frases de perigo
Declarações de precaução
Classificações de perigo
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
Órgãos-alvo
Central nervous system, Respiratory system
Perigos de suplementos
Código de classe de armazenamento
3 - Flammable liquids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
1.4 °F
Ponto de fulgor (°C)
-17 °C
Equipamento de proteção individual
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Salt additives increase both the rate and the efficiency of the Mg-halogen exchange reaction. The most effective reagents are generated with R-MgCl (R = i-Pr, s-Butyl) and 1.0 equiv of LiCl.
Transformative reagents enable selective conversions within molecules containing sensitive functionalities under mild reactions.
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How is shipping temperature determined? And how is it related to the product storage temperature?
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How can I determine the shelf life / expiration / retest date of this product?
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfHelpful?
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