13468

2-Phenyl-1,3-dioxan-5-ol

mixture of cis and trans, ≥97.0% (HPLC)

• Sinônimo(s): 1,3-O-Benzylideneglycerol
• Fórmula empírica (Notação de Hill): C₁₀H₁₂O₃
• Número CAS: 1708-40-3
• Peso molecular: 180.20
• Beilstein: 84059
• Número CE: 216-963-7
• Número MDL: MFCD00047504
• Código UNSPSC: 12352100
• ID de substância PubChem: 57647095
• NACRES: NA.22

Propriedades

• Nível de qualidade: 100
• Ensaio: ≥97.0% (HPLC)
• Formulário: powder
• grupo funcional: ether; hydroxyl; phenyl
• temperatura de armazenamento: 2-8°C
• cadeia de caracteres SMILES: OC1COC(OC1)c2ccccc2
• InChI: 1S/C10H12O3/c11-9-6-12-10(13-7-9)8-4-2-1-3-5-8/h1-5,9-11H,6-7H2
• chave InChI: BWKDAAFSXYPQOS-UHFFFAOYSA-N

Descrição

Descrição geral

cis-2-phenyl-1,3-dioxan-5-ol reacts with triphenylphosphine-carbon tetrabromide to yield cis-4-bromomethyl-2-phenyl-1,3-dioxolan, its trans-diastereoisomer and trans-5-bromo-2-phenyl-1,3-dioxan[1].

Aplicação

2-Phenyl-1,3-dioxan-5-ol can be used as a starting material in the synthesis of 5-benzyloxy1,3-dioxan-2-one (a carbonate of glycerol monomer). It undergoes ring-opening polymerization with ε-caprolactone in presence of tin(II) 2-ethylhexanoate (Sn(oct)₂).[2]

2-Phenyl-1,3-dioxan-5-ol was used as starting reagent in the synthesis of carbonate of glycerol monomer, 5-benzyloxy-1,3-dioxan-2-one which forms copolymers with ε-caprolactone[2].

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: Eyeshields, Gloves, type N95 (US)