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Documentos Principais

383317

Sigma-Aldrich

Zinc acetate

99.99% trace metals basis

Sinônimo(s):

Zn(OAc)2

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About This Item

Fórmula linear:
(CH3CO2)2Zn
Número CAS:
Peso molecular:
183.48
Número CE:
Número MDL:
Código UNSPSC:
12161600
ID de substância PubChem:
NACRES:
NA.22

Nível de qualidade

Ensaio

99.99% trace metals basis

Formulário

solid

adequação da reação

core: zinc
reagent type: catalyst

Impurezas

<0.2% water

densidade

1.84 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

CC(O[Zn]OC(C)=O)=O

InChI

1S/2C2H4O2.Zn/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

chave InChI

DJWUNCQRNNEAKC-UHFFFAOYSA-L

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Descrição geral

Zinc acetate is primarily utilized as a precursor or catalyst in various synthetic reactions. In organic chemistry, zinc acetate finds application as a reagent in the formation of carbon-carbon bonds. It can facilitate the synthesis of esters, allylic alcohols, and acetals. For example, it can promote the acylation of alcohols, phenols, and amines to form esters, such as the Fischer esterification reaction. Zinc acetate has also been used in the synthesis of metal-organic frameworks (MOFs). MOFs are porous materials consisting of metal ions or clusters coordinated to organic ligands. Zinc acetate can act as a precursor for the formation of MOFs due to its ability to coordinate with organic linkers and form robust networks.

For small scale and high throughput uses, product is also available as ChemBeads (927805)

Aplicação

Zinc acetate has been used in:
  • Synthesis of layered Zn-arylphosphonates with potential application in sorption, ion exchange or catalysis.
  • Ultrasonic preparation of zinc sulfide nanoparticles coated on silica particles.
  • Synthesis of ZnO/ZnS composites throughion exchange method (1)
  • Fabrication of 3D hierarchical ZnO/ZnSheterojunction branched nanowires for enhanced photoelectrochemical watersplitting (2)
  • Synthesis of Co3O4-decorated ZnO@ZnS core-shellstructures for efficient photocatalytic overall water splitting (3)
  • Synthesis of ZnO photocatalysts (4)

Nota de preparo

Preparation of ZnSe nanostructures upon thermolysis of zinc acetate and selenourea in a mixture of octadecylamine and trioctylphosphine oxide.

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

dust mask type N95 (US), Eyeshields, Gloves


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