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C31104

Sigma-Aldrich

3-Chlor-2-Chlormethyl-1-Propen

99%

Synonym(e):

1,1-Bis-(chlormethyl)-ethylen, Methallyldichlorid

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€ 161,00
50 G
€ 409,00

€ 161,00


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10 G
€ 161,00
50 G
€ 409,00

About This Item

Lineare Formel:
CH2=C(CH2Cl)2
CAS-Nummer:
Molekulargewicht:
125.00
Beilstein:
1560178
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22

€ 161,00


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Dampfdichte

3.12 (vs air)

Qualitätsniveau

Assay

99%

Form

liquid

Selbstzündungstemp.

896 °F

Expl.-Gr.

8.1 %

Brechungsindex

n20/D 1.4753 (lit.)

bp

138 °C (lit.)

mp (Schmelzpunkt)

−14 °C (lit.)

Dichte

1.08 g/mL at 25 °C (lit.)

Lagertemp.

2-8°C

SMILES String

ClCC(=C)CCl

InChI

1S/C4H6Cl2/c1-4(2-5)3-6/h1-3H2

InChIKey

XJFZOSUFGSANIF-UHFFFAOYSA-N

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Anwendung

3-Chloro-2-chloromethyl-1-propene can be used in the synthesis of 2,11-bis(methylidene)spermine, an inhibitor of spermine oxidase[1] and branched side chains of conjugated polymers.[2][3] It can also be used in the intermolecular [2+2] photocycloaddition during the total synthesis of (−)-grandisol.[4]

Piktogramme

FlameSkull and crossbones

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 3

Flammpunkt (°F)

96.8 °F

Flammpunkt (°C)

36 °C

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Kunden haben sich ebenfalls angesehen

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Enantioselective Intermolecular [2+ 2] Photocycloaddition Reaction of Cyclic Enones and Its Application in a Synthesis of (−)-Grandisol.
Poplata S and Bach T
Journal of the American Chemical Society, 140(9), 3228-3231 (2018)
Synthesis of 2, 11-bis (methylidene) spermine, a new inhibitor of spermine oxidase.
Grigorenko N A, et al.
Russian Journal of Bioorganic Chemistry, 42(4), 423-427 (2016)
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Liquid crystalline (LC) elastomers (LCEs) enable large-scale reversible shape changes in polymeric materials; however, they require intensive, irreversible programming approaches in order to facilitate controllable actuation. We have implemented photoinduced dynamic covalent chemistry (DCC) that chemically anneals the LCE toward

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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