397326

Tetrakis(diethylamido)zinn(IV)

• Synonym(e): Tetrakis-(diethylamino)-Zinn(IV)
• Lineare Formel: [(C₂H₅)₂N]₄Sn
• CAS-Nummer: 1066-78-0
• Molekulargewicht: 407.23
• MDL-Nummer: MFCD00239515
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24864701
• NACRES: NA.23

Eigenschaften

• Form: liquid
• Eignung der Reaktion: core: tin
• Brechungsindex: n20/D 1.49 (lit.)
• bp: 110 °C/0.5 mmHg (lit.)
• Dichte: 1.125 g/mL at 25 °C (lit.)
• SMILES String: CCN(CC)[Sn](N(CC)CC)(N(CC)CC)N(CC)CC
• InChI: 1S/4C4H10N.Sn/c4*1-3-5-4-2;/h4*3-4H2,1-2H3;/q4*-1;+4
• InChIKey: IFVSPCQTOMZHOP-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Tetrakis(diethylamido)tin(IV) is a volatile compound with four exchangeable ligands. It is widely used as a precursor to produce metal oxide thin films by the chemical vapor deposition method.

Anwendung

Tetrakis(diethylamido)tin(IV) can be used:

• As a precursor to synthesize mesoporous tin silicate xerogels via non-hydrolytic templated sol–gel synthesis. These xerogels are potential catalysts for aminolysis and for the Meerwein–Ponndorf–Verley reduction.
• To produce stable metal oxide thin films on the surface of carbon electrode materials.
• To fabricate an ultrathin layer of SnO₂ on carbon nanotubes, which can be used as anodes for lithium-ion batteries. This ultrathin layer helps to enhance the cycling stability and rate capability of anodes.

Sicherheitshinweise

• Piktogramme: GHS02,GHS06,GHS05
• Signalwort: Danger
• H-Sätze: H226,H301 + H311 + H331,H318
• P-Sätze: P210 - P280 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P311 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 3
• Zusätzliche Gefahrenhinweise: EUH014
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 102.2 °F - closed cup
• Flammpunkt (°C): 39 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter