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902225

Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6

≥95%

别名:

Photocatalyst

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100 MG
$330.00

$330.00

预计发货时间2025年5月22日详情

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100 MG
$330.00

About This Item

经验公式（希尔记法）:
C36H22F16IrN4P
CAS号:
2229858-27-7
分子量:
1037.75
MDL编号:
MFCD32857514
UNSPSC代码:
41141700
NACRES:
NA.22

$330.00

预计发货时间2025年5月22日详情

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方案

≥95%

表单

powder

反应适用性

core: iridium
reaction type: Photocatalysis
reagent type: catalyst

mp

>300 °C

SMILES字符串

FC1=CC(F)=C2C3=CC=C(C=[N]3[Ir+3]45([C-]2=C1)([C-]6=CC(F)=CC(F)=C6C7=CC=C(C=[N]74)C)[N]8=CC=C(C=C8C=9C=C(C=C[N]95)C(F)(F)F)C(F)(F)F)C.[F-][P+5]([F-])([F-])([F-])([F-])[F-]

InChI

InChI=1S/C12H6F6N2.2C12H8F2N.F6P.Ir/c13-11(14,15)7-1-3-19-9(5-7)10-6-8(2-4-20-10)12(16,17)18;2*1-8-2-5-12(15-7-8)10-4-3-9(13)6-11(10)14;1-7(2,3,4,5)6;/h1-6H;2*2-3,5-7H,1H3;;/q;3*-1;+3

InChI key

RYKRFKQFYGHADE-UHFFFAOYSA-N

相关类别

应用

Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF3 (901466) and supersilanol (902489).

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

其他说明

A radical approach to the copper oxidative addition problem:Trifluoromethylation of bromoarenes

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Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%

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Ir(dFFppy)2(dtbbpy)PF6

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(Ir[Me(Me)ppy]2(dtbpy))PF6

908568

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6, ≥95%

908703

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6, ≥95%

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[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6 , ≥95%

912948

Ir[FCF3(CF3)ppy]2(dtbbpy)PF6

922897

[Ir(ppy)2(5,5′-Me2bpy)]PF6, ≥95%

925497

[Ir(dFOMeppy)2(dtbbpy)]PF6, ≥95%

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCJ9415

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Chip Le et al.
Science (New York, N.Y.), 360(6392), 1010-1014 (2018-06-02)
Transition metal-catalyzed arene functionalization has been widely used for molecular synthesis over the past century. In this arena, copper catalysis has long been considered a privileged platform due to the propensity of high-valent copper to undergo reductive elimination with a

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