跳转至内容
Merck
所有图片(3)

文件

902489

Sigma-Aldrich

三（三甲基甲硅烷基）硅烷醇

≥95%

别名:

(TMS)3SiOH, 1,1,1,3,3,3-六甲基-2-（三甲基甲硅烷基）三硅烷基-2-醇, 超硅醇, （羟基-双（三甲基硅烷基）甲硅烷基）-三甲基硅烷

登录查看公司和协议定价
所有图片(3)

About This Item

经验公式（希尔记法）:
C9H28OSi4
CAS号:
7428-60-6
分子量:
264.66
MDL號碼:
MFCD00093727
分類程式碼代碼:
12161700
NACRES:
NA.22

化驗

≥95%

形狀

liquid

反應適用性

reaction type: C-C Bond Formation

折射率

n/D 1.496

密度

0.859 g/mL

InChI

1S/C9H28OSi4/c1-11(2,3)14(10,12(4,5)6)13(7,8)9/h10H,1-9H3

InChI 密鑰

ABTWCNHNRLMBFR-UHFFFAOYSA-N

相关类别

應用

在双催化铜/光致氧化还原迅速发展的形势下，MacMillan实验室已证明该超级硅烷醇是用于通过烷基卤化物和芳基卤化物的三氟甲基化大量产生烷基-CF3和芳基-CF3 的一种极佳试剂。在这两种情况下，这些反应均具有较宽的底物范围和良好的官能团耐受性。更具体地说，在温和条件下，各种五元和六元杂芳基卤化物可以容易地转化为相应的三氟甲基杂芳烃。与dMesSCF3 （901466）和Ir光催化剂（902217 或 902225）结合使用。

其他說明

一种彻底解决铜氧化加成问题的方法：溴代芳烃的三氟甲基化

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

200.3 °F

閃點（°C）

93.5 °C

Choose from one of the most recent versions:

分析证书(COA)

Lot/Batch Number
MKCW0225
MKCW6219
MKCS7963
MKCQ7737
MKCN9702

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

Annie J Jiang et al.
Journal of the American Chemical Society, 131(46), 16630-16631 (2009-11-19)
Mo and W MonoAryloxide-Pyrrolide (MAP) olefin metathesis catalysts can couple terminal olefins to give as high as >98% Z-products in moderate to high yields with as little as 0.2% catalyst. Results are reported for 1-hexene, 1-octene, allylbenzene, allyltrimethylsilane, methyl-10-undecenoate, methyl-9-decenoate
Timothy J Boyle et al.
Inorganic chemistry, 57(15), 8806-8820 (2018-07-07)
In an effort to generate single-source precursors for the production of metal-siloxide (MSiO x) materials, the tris(trimethylsilyl)silanol (H-SST or H-OSi(SiMe3)3 (1) ligand was reacted with a series of group 4 and 5 metal alkoxides. The group 4 products were crystallographically
Chip Le et al.
Science (New York, N.Y.), 360(6392), 1010-1014 (2018-06-02)
Transition metal-catalyzed arene functionalization has been widely used for molecular synthesis over the past century. In this arena, copper catalysis has long been considered a privileged platform due to the propensity of high-valent copper to undergo reductive elimination with a

我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系技术服务部门