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Merck

908703

Sigma-Aldrich

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6

≥95%

别名:

[(4,4′-di-tert-butyl-2,2′-bipyridine)-bis-(5-methyl-2-(5-fluoro-phenyl)-pyridine)-iridium(III)] hexafluorophosphate

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100 MG
$261.00
500 MG
$848.00

$261.00


预计发货时间2025年7月04日详情


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100 MG
$261.00
500 MG
$848.00

About This Item

经验公式(希尔记法):
C42H42F8IrN4P
分子量:
977.99
MDL编号:
UNSPSC代码:
12352101
NACRES:
NA.22

$261.00


预计发货时间2025年7月04日详情


获取大包装报价

方案

≥95%

表单

powder or crystals

反应适用性

reaction type: Photocatalysis
reagent type: catalyst

光触媒活化

450 nm

InChI key

SNWREQGMGVVZPS-UHFFFAOYSA-N

应用

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

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Yufan Liang et al.
Nature, 559(7712), 83-88 (2018-06-22)
Over the past three decades, considerable progress has been made in the development of methods to construct sp2 carbon-nitrogen (C-N) bonds using palladium, copper or nickel catalysis1,2. However, the incorporation of alkyl substrates to form sp3 C-N bonds remains one
Yong Yao Loh et al.
Science (New York, N.Y.), 358(6367), 1182-1187 (2017-11-11)
Deuterium- and tritium-labeled pharmaceutical compounds are pivotal diagnostic tools in drug discovery research, providing vital information about the biological fate of drugs and drug metabolites. Herein we demonstrate that a photoredox-mediated hydrogen atom transfer protocol can efficiently and selectively install
Andrew G Capacci et al.
Nature chemistry, 9(11), 1073-1077 (2017-10-25)
Although the α-alkylation of ketones has already been established, the analogous reaction using aldehyde substrates has proven surprisingly elusive. Despite the structural similarities between the two classes of compounds, the sensitivity and unique reactivity of the aldehyde functionality has typically

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