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Merck

574082

Sigma-Aldrich

Chromium(III) acetylacetonate

99.99% trace metals basis

Synonim(y):

Chromium(III) 2,4-pentanedionate, Cr(acac)3

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About This Item

Wzór liniowy:
Cr(C5H7O2)3
Numer CAS:
Masa cząsteczkowa:
349.32
Beilstein:
4148971
Numer WE:
Numer MDL:
Kod UNSPSC:
12352300
Identyfikator substancji w PubChem:
NACRES:
NA.23

Próba

99.99% trace metals basis

Formularz

solid

przydatność reakcji

core: chromium

bp

340 °C (lit.)

mp

210 °C (lit.)

ciąg SMILES

CC(=O)\C=C(\C)O[Cr](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Cr/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

Klucz InChI

JWORPXLMBPOPPU-LNTINUHCSA-K

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Opis ogólny

Chromium(III) acetylacetonate is an acidopentamminechromium (111) salt, which is a crystalline material that can be prepared by treatment of precipitated hydrous chromium(III) oxide with acetylacetone.[1]

Zastosowanie

Chromium(III) acetylacetonate may be used as an active site in the formation of redox systems for the fabrication of flow batteries.[2] It may also be used as a precursor for chromium nitride based metallic coatings.[3]

Komentarz do analizy

Used to modify the surface properties of solid polyurethanes formed in its presence.
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Piktogramy

Exclamation mark

Hasło ostrzegawcze

Warning

Zwroty wskazujące rodzaj zagrożenia

Klasyfikacja zagrożeń

Eye Irrit. 2 - Skin Irrit. 2

Kod klasy składowania

11 - Combustible Solids

Klasa zagrożenia wodnego (WGK)

WGK 2

Temperatura zapłonu (°F)

>392.0 °F

Temperatura zapłonu (°C)

> 200 °C

Środki ochrony indywidualnej

dust mask type N95 (US), Eyeshields, Gloves


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Certyfikaty analizy (CoA)

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Dokumenty związane z niedawno zakupionymi produktami zostały zamieszczone w Bibliotece dokumentów.

Odwiedź Bibliotekę dokumentów

Plasma assisted metal-organic chemical vapor deposition of hard chromium nitride thin film coatings using chromium (III) acetylacetonate as the precursor
Dasgupta A, et al.
Materials Science & Engineering. A, Structural Materials : Properties, Microstructure and Processing, 374(1-2), 362-368 (2004)
Chromium (III) acetylacetonate
Fernelius WC, et al.
Inorganic Syntheses, 5, 130-131 (1957)
Non-aqueous chromium acetylacetonate electrolyte for redox flow batteries
Liu Q, et al.
Electrochemical Communications, 12(11), 1634-1637 (2010)
Chiara Allegretti et al.
Molecules (Basel, Switzerland), 25(12) (2020-06-27)
Technical lignins, typically obtained from the biorefining of lignocellulosic raw materials, represent a highly abundant natural aromatic feedstock with high potential in a sustainable economy scenario, especially considering the huge primary production volumes and the inherently renewable nature of this
Channa R De Silva et al.
Journal of the American Chemical Society, 131(18), 6336-6337 (2009-04-17)
Nearly monodisperse lanthanide-doped magnetite nanoparticles were obtained by thermally decomposing a mixture of Fe(acac)(3) and Ln(acac)(3) (acac = acetylacetonate; Ln = Sm, Eu, Gd) in the presence of passivating surfactants. Magnetic studies revealed room-temperature ferromagnetic behaviors of these doped nanoparticles

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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