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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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377155
Chlorobis(cyclooctene)iridium(I)dimer
97%
Synonim(y):
[Ir(coe)2Cl]2, Di-μ-chlorotetrakis(cyclooctene)diiridium
Wybierz wielkość
392,00 zł
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About This Item
392,00 zł
Polecane produkty
Poziom jakości
Próba
97%
Formularz
powder
przydatność reakcji
core: iridium
reagent type: catalyst
mp
160-165 °C (dec.) (lit.)
ciąg SMILES
Cl[Ir].Cl[Ir].[CH]1[CH]CCCCCC1.[CH]2[CH]CCCCCC2.[CH]3[CH]CCCCCC3.[CH]4[CH]CCCCCC4
InChI
1S/4C8H14.2ClH.2Ir/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;;
Klucz InChI
WBRREXQCZAFSKS-XFCUKONHSA-L
Powiązane kategorie
Zastosowanie
- Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand
- Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions
- Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions
- Alkylation reactions
- Guerbet reaction
- Allylic amination reactions in a DNA-diene-iridium(I) hybrid system
- Asymmetric hydroamination reactions
- Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand.[1]
- Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions.[2]
- Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions.[3]
- Alkylation reactions.[4]
- Guerbet reaction.[5]
- Allylic amination reactions using a DNA-diene-iridium(I) hybrid system.[6]
- Asymmetric hydroamination reactions.[7]
Hasło ostrzegawcze
Warning
Zwroty wskazujące rodzaj zagrożenia
Zwroty wskazujące środki ostrożności
Klasyfikacja zagrożeń
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Organy docelowe
Respiratory system
Kod klasy składowania
11 - Combustible Solids
Klasa zagrożenia wodnego (WGK)
WGK 3
Temperatura zapłonu (°F)
Not applicable
Temperatura zapłonu (°C)
Not applicable
Środki ochrony indywidualnej
dust mask type N95 (US), Eyeshields, Gloves
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Produkty
Kwasy aryloboronowe i estry, istotne narzędzia w transformacjach chemicznych, znajdują szerokie zastosowanie, szczególnie w reakcji krzyżowego sprzęgania Suzuki-Miyaura.
Arylboronic acids and esters, vital tools in chemical transformations, find extensive use, particularly in the Suzuki-Miyaura cross-coupling reaction.
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfHelpful?
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