If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
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377155
Chlorobis(cyclooctene)iridium(I)dimer
97%, powder
Synonim(y):
[Ir(coe)2Cl]2, Di-μ-chlorotetrakis(cyclooctene)diiridium
Wybierz wielkość
| Rozmiar/SKU | Dostępność | Cena netto |
|---|---|---|
250 mg | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 410,00 zł |
1 g | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 1030,00 zł |
5 g | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 4930,00 zł |
Informacje o tej pozycji
410,00 zł
Nazwa produktu
Chlorobis(cyclooctene)iridium(I)dimer, 97%
Quality Segment
assay
97%
form
powder
reaction suitability
core: iridium, reagent type: catalyst
mp
160-165 °C (dec.) (lit.)
SMILES string
Cl[Ir].Cl[Ir].[CH]1[CH]CCCCCC1.[CH]2[CH]CCCCCC2.[CH]3[CH]CCCCCC3.[CH]4[CH]CCCCCC4
InChI
1S/4C8H14.2ClH.2Ir/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;;
InChI key
WBRREXQCZAFSKS-XFCUKONHSA-L
Application
- Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand
- Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions
- Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions
- Alkylation reactions
- Guerbet reaction
- Allylic amination reactions in a DNA-diene-iridium(I) hybrid system
- Asymmetric hydroamination reactions
- Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand.
- Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions.
- Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions.
- Alkylation reactions.
- Guerbet reaction.
- Allylic amination reactions using a DNA-diene-iridium(I) hybrid system.
- Asymmetric hydroamination reactions.
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Ta pozycja | |||
|---|---|---|---|
| description 97% | description 98% | description Umicore, 97% | description - |
| reaction suitability reagent type: catalyst, core: iridium | reaction suitability reagent type: catalyst, core: rhodium | reaction suitability reaction type: C-H Activation, core: iridium, reagent type: catalyst | reaction suitability reagent type: catalyst, core: iridium |
| assay 97% | assay 98% | assay 97% | assay - |
| form powder | form powder | form powder | form powder or crystals |
| Quality Level 100 | Quality Level 100 | Quality Level 200 | Quality Level - |
| mp 160-165 °C (dec.) (lit.) | mp 190 °C (dec.) (lit.) | mp 205 °C (dec.) (lit.) | mp 150-155 °C (dec.) |
Słowo ostrzegawcze
Warning
Kody zagrożeń
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Narządy docelowe
Respiratory system
Klasa składowania
11 - Combustible Solids
Co się dzieje?
WGK 3
Temperatura zapłonu (°F)
Not applicable
Temperatura zapłonu (°C)
Not applicable
PPE (środki ochrony indywidualnej)
dust mask type N95 (US), Eyeshields, Gloves
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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