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Merck

203548

Sigma-Aldrich

Lanthanum(III) nitrate hexahydrate

99.999% trace metals basis

Synonim(y):

Nitric acid, lanthanum (III) salt, hexahydrate

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25 G
594,00 zł
100 G
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500 G
5160,00 zł

594,00 zł


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25 G
594,00 zł
100 G
1390,00 zł
500 G
5160,00 zł

About This Item

Wzór liniowy:
La(NO3)3 · 6H2O
Numer CAS:
Masa cząsteczkowa:
433.01
Numer WE:
Numer MDL:
Kod UNSPSC:
12352302
Identyfikator substancji w PubChem:
NACRES:
NA.23
Próba:
99.999% trace metals basis
Formularz:
solid

594,00 zł


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Poproś o zamówienie zbiorcze

Poziom jakości

Próba

99.999% trace metals basis

Formularz

solid

przydatność reakcji

reagent type: catalyst
core: lanthanum

zanieczyszczenia

≤15.0 ppm Trace Rare Earth Analysis

mp

65-68 °C

ciąg SMILES

[La+3].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/La.3NO3.6H2O/c;3*2-1(3)4;;;;;;/h;;;;6*1H2/q+3;3*-1;;;;;;

Klucz InChI

GJKFIJKSBFYMQK-UHFFFAOYSA-N

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Opis ogólny

Lanthanum(III) nitrate hexahydrate is a transition metal catalyst widely used in many organic transformations such as chemoselective deprotection of acetonides, acetylation of alcohols, phenols, and amines with acetic anhydride, and synthesis of α-amino nitriles. It can also be used as a precursor in the preparation of lanthanum-based nanoparticles.

Zastosowanie

Lanthanum(III) nitrate hexahydrate can be used as a catalyst in the synthesis of:
  • α-aminonitriles by a one-pot three-component coupling of the carbonyl compound, amine, and TMSCN.
  • Acetals and geminal diacetates (acylals)from aldehydes.
  • Bis(indolyl) methanes under solvent‐free conditions.
It can also be used as a starting material for the electrochemical synthesis of LaMnO3 thin films and solvothermal synthesis of doped lanthanide oxysulfide (La2O2S).

Cechy i korzyści

  • Thermal stability
  • Low toxicity
  • Mild reaction condition
  • Chemoselectivity
  • Low cost
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Hasło ostrzegawcze

Danger

Zwroty wskazujące rodzaj zagrożenia

Zwroty wskazujące środki ostrożności

Klasyfikacja zagrożeń

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 2

Kod klasy składowania

5.1B - Oxidizing hazardous materials

Klasa zagrożenia wodnego (WGK)

WGK 2

Środki ochrony indywidualnej

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Dokumenty związane z niedawno zakupionymi produktami zostały zamieszczone w Bibliotece dokumentów.

Odwiedź Bibliotekę dokumentów

J Tyler Mefford et al.
Physical chemistry chemical physics : PCCP, 21(6), 3327-3338 (2019-01-29)
Perovskite oxides are active room-temperature bifunctional oxygen electrocatalysts in alkaline media, capable of performing the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) with lower combined overpotentials relative to their precious metal counterparts. However, their semiconducting nature necessitates the
Wen-Feng Zhao et al.
Dalton transactions (Cambridge, England : 2003), 41(33), 10091-10096 (2012-08-02)
The reaction between polyoxometalate (POM) [TBA](12)[WZn{Zn(H(2)O)}(2)(ZnW(9)O(34))(2)] (TBA = tetrabutyl ammonium) and lanthanide (Ln) nitrate (Ln = La, Eu and Tb) in a mixed solvent of CH(3)CN and DMF yielded three noncentrosymmetric diamondoid Ln-POM solid materials, {[Ln(2)(DMF)(8)(H(2)O)(6)][ZnW(12)O(40)]}·4DMF (Ln-POM; Ln = La
Emanuela Mazzon et al.
Shock (Augusta, Ga.), 25(5), 515-521 (2006-05-09)
Small intestine permeability is frequently altered in inflammatory bowel diseases and may be caused by the translocation of intestinal toxins through leaky small intestine tight junctions (TJs) and adherence. Thus, the aim of the present study was to examine the
L P Lopatina et al.
Biofizika, 50(6), 1120-1124 (2005-12-20)
The influence of lanthanoids on exocytosis was investigated. It was shown that gadolinium increases the spontaneous release of the glutamate nonmetabolizing analogue [3H]D-aspartate. It was established using the fluorescent dye acridine orange that gadolinium and lanthanum induce exocytosis. The effect
H G Nóblega et al.
Comparative biochemistry and physiology. Part A, Molecular & integrative physiology, 144(1), 119-124 (2006-04-11)
The aim of this study was to investigate the ultrastructure of the interface zone between the nervous tissue and the connective vascular sheath that surround the central ganglia of the terrestrial snail of Megalobulimus abbreviatus and test its permeability using

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Rare earth elements are vital in everyday life worldwide: catalysts in cars, colors in screens, magnets in electronics. Essential for modern living.

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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