667811

(−)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane

• 実験式（ヒル表記法）: C₃₄H₃₆P₂
• CAS番号: 528565-79-9
• 分子量: 506.60
• MDL番号: MFCD07369027
• UNSPSCコード: 12352005
• PubChem Substance ID: 24884944
• NACRES: NA.22

特性

• フォーム: solid
• 品質水準: 100
• mp: 143-147 °C
• 官能基: phenyl; phosphine
• SMILES記法: C1C[C@@H](P(CCP2[C@H](CC[C@@H]2c3ccccc3)c4ccccc4)[C@H]1c5ccccc5)c6ccccc6
• InChI: 1S/C34H36P2/c1-5-13-27(14-6-1)31-21-22-32(28-15-7-2-8-16-28)35(31)25-26-36-33(29-17-9-3-10-18-29)23-24-34(36)30-19-11-4-12-20-30/h1-20,31-34H,21-26H2/t31-,32-,33-,34-/m1/s1
• InChI Key: VHHAZLMVLLIMHT-YFRBGRBWSA-N

詳細

アプリケーション

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

(−)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane can be used:

• As a chiral ligand in the 1,3-dipolar cycloaddition reaction of azomethyne yielded [70]fullerene enantiomers; catalyzed by silver.[1]
• As a component of the catalytic system along with silver, which is used for the synthesis of fullerene hybrids.[2]

法的情報

Sold in collaboration with Namena Corp. for research purposes only.

安全性情報

• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable