553344

Isopropyl isocyanide

97%

• 別名: 2-Isocyanopropane, 2-Propyl isonitrile, Isopropyl isonitrile
• 化学式: (CH₃)₂CHNC
• CAS番号: 598-45-8
• 分子量: 69.11
• MDL番号: MFCD00015503
• UNSPSCコード: 12352100
• PubChem Substance ID: 24879320
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: 97%
• 屈折率: n20/D 1.371 (lit.)
• bp: 75 °C (lit.)
• 密度: 0.733 g/mL at 25 °C (lit.)
• 官能基: amine; isonitrile
• 保管温度: 2-8°C
• SMILES記法: CC(C)[N+]#[C-]
• InChI: 1S/C4H7N/c1-4(2)5-3/h4H,1-2H3
• InChI Key: MJZUMMKYWBNKIP-UHFFFAOYSA-N

詳細

詳細

Isopropyl isocyanide is an alkyl isocyanide.

アプリケーション

Isopropyl isocyanide may be used in the preparation of:

• Ugi ligand A2C11I1, which is employed in the solid-phase Ugi synthesis.[1]
• Pentafluorophenyl (PFP) functional monomers, via Passerini reaction.[2]
• Dinuclear copper complex [Cu₂(μ-PiPr₂bipy)₂{μ-CNCH(CH₃)₂}](PF₆)₂ [PiPr₂bipy = 6-(diisopropylphosphanyl)-2,2′-bipyridine].[3]
• (3E)-(Imino)thiaisoindoline 1,1-dioxide derivative.[4]
• N,N′-diisopropylcarbodiimide (DIC) analog via reaction with propan-2-amine.[5]
• 1-t-butyl-2-isopropyldiaziridinone via reaction with 2-methyl-2-nitrosopropane[6]
• isopropyl isocyanate via reaction with ozone[7]
• 1-phthalimidoazetidines via [1+3]cycloaddition reaction with 1-pththalimidoaziridines[8]

安全性情報

• ピクトグラム: GHS02,GHS06
• シグナルワード: Danger
• 危険有害性情報: H225,H301 + H311 + H331
• 注意書き: P210 - P233 - P280 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P311
• 危険有害性の分類: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 3
• 引火点(°F): 69.1 °F - closed cup
• 引火点(℃): 20.6 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter