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B-023

Supelco

BSTFA

with 1% TMCS, kit of 10 × 1 mL, analytical standard, Cerilliant®

Sinonimo/i:

BSTFA

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About This Item

Formula condensata:
CF3C[=NSi(CH3)3]OSi(CH3)3
Numero CAS:
Peso molecolare:
257.40
Beilstein:
2050024
Numero MDL:
Codice UNSPSC:
41116107
ID PubChem:
NACRES:
NA.24
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Nome del prodotto

N,O-bis(trimetilsilil)trifluoroacetamide, kit of 10 × 1 mL, analytical standard, Cerilliant®

Grado

analytical standard

Livello qualitativo

Impiego in reazioni chimiche

reagent type: derivatization reagent
reaction type: Acylations

Confezionamento

kit of 10 × 1 mL

Produttore/marchio commerciale

Cerilliant®

tecniche

gas chromatography (GC): suitable

Indice di rifrazione

n20/D 1.384 (lit.)

P. ebollizione

45-50 °C/14 mmHg (lit.)

Densità

0.969 g/mL at 25 °C (lit.)

applicazioni

forensics and toxicology

Formato

neat

Temperatura di conservazione

−20°C

Stringa SMILE

C[Si](C)(C)O\C(=N\[Si](C)(C)C)C(F)(F)F

InChI

1S/C8H18F3NOSi2/c1-14(2,3)12-7(8(9,10)11)13-15(4,5)6/h1-6H3/b12-7+
XCOBLONWWXQEBS-KPKJPENVSA-N

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Applicazioni

BSTFA (with 1% TMCS) may be used as a derivatizing agent in the following:
  • Analysis of estrogenic compounds in water samples using gas chromatography coupled to mass spectrometry (GC-MS).[1]
  • Quantification of α-pyrrolidinovalerophenone (α-PVP) and its metabolites in urine samples using gas chromatography coupled to mass spectrometry (GC-MS).[2]

Caratteristiche e vantaggi

  • BSTFA is very versatile, reacting with a range of polar organic compounds and replacing active hydrogens with a −Si(CH3)3 (trimethylsilyl) group.
  • Reacts rapidly and more completely than BSA.;
  • TMCS increases the reactivity of BSTFA (or other silylation reagents).
  • Amides and many secondary amines and hindered hydroxyls, incompletely derivatized by BSTFA alone, can be derivatized by adding 1-20% TMCS to BSTFA.
  • Has good solvent properties and can function as a silylation reagent without additional solvents.
  • Alternatively, the mixture is very soluble in most commonly used silylation solvents.

Note legali

CERILLIANT is a registered trademark of Merck KGaA, Darmstadt, Germany

Pittogrammi

FlameExclamation mark

Avvertenze

Warning

Indicazioni di pericolo

Classi di pericolo

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

75.2 °F - closed cup

Punto d’infiammabilità (°C)

24.0 °C - closed cup


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Certificati d'analisi (COA)

Lot/Batch Number

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Optimisation of derivatisation for the analysis of estrogenic compounds in water by solid-phase extraction gas chromatography--mass spectrometry
Zhang LZ, et al.
Analytica Chimica Acta, 577(1), 52-61 (2006)
Determination of synthetic cathinone $\alpha$-pyrrolidinovalero-phenone and its metabolite in urine using solid-phase extraction and gas chromatography--mass spectrometry
Cheng WK, et al.
Rapid Communications in Mass Spectrometry, 34(1), e8579-e8579 (2020)

Domande

1–2 di 2 domande  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 risposta
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 risposta
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Utile?

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