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Merck

06735

Supelco

tert-Butyl(chlor)dimethylsilan

for GC derivatization, LiChropur, ≥99.0% (GC)

Synonym(e):

tert-Butyldimethylchlorsilan, tert-Butyldimethylsilylchlorid, TBDMSCl

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About This Item

Lineare Formel:
(CH3)3CSi(CH3)2Cl
CAS-Nummer:
Molekulargewicht:
150.72
Beilstein:
505999
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
41116105
PubChem Substanz-ID:
NACRES:
NA.22

Qualität

for GC derivatization
LiChropur

Qualitätsniveau

Assay

≥99.0% (GC)

Eignung der Reaktion

reagent type: derivatization reagent
reaction type: Silylations

Methode(n)

gas chromatography (GC): suitable

bp

125 °C (lit.)

mp (Schmelzpunkt)

86-89 °C (lit.)

SMILES String

CC(C)(C)[Si](C)(C)Cl

InChI

1S/C6H15ClSi/c1-6(2,3)8(4,5)7/h1-5H3

InChIKey

BCNZYOJHNLTNEZ-UHFFFAOYSA-N

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Rechtliche Hinweise

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

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Signalwort

Danger

Gefahreneinstufungen

Aquatic Chronic 2 - Eye Dam. 1 - Flam. Sol. 1 - Skin Corr. 1A

Lagerklassenschlüssel

4.1B - Flammable solid hazardous materials

WGK

WGK 2

Flammpunkt (°F)

71.6 °F - closed cup

Flammpunkt (°C)

22 °C - closed cup


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Some observations on the t-butyldimethylchlorosilane derivatization reaction.
K Bricknell et al.
Biochemical medicine, 23(1), 119-121 (1980-02-01)
P Huttenloch et al.
Environmental science & technology, 35(21), 4260-4264 (2001-11-23)
The efficacy of the surface modification of natural diatomite and zeolite material by chlorosilanes is demonstrated. Chlorosilanes used were trimethylchlorosilane (TMSCI), tert-butyldimethylchlorosilane (TBDMSCI), dimethyloctadecylchlorosilane (DMODSCI), and diphenyldichlorosilane (DPDSCI) possessing different headgroups and chemical properties. Silanol groups of the diatomite and
C Tellis et al.
Journal of biochemistry, 119(4), 823-827 (1996-04-01)
1-O-Hexadecyl-2-acetyl-sn-glycerol, the immediate precursor of platelet- activating factor (PAF) in its de novo formation, was detected in the protozoon Tetrahymena pyriformis. It was purified from the total lipid extract by TLC, after successive developments in two different solvent systems. Characterization
Eva C Hartmann et al.
Archives of toxicology, 85(6), 601-606 (2010-10-19)
A dose of 0.99 mg d(3)-acrylamide (d(3)-AA) (13.2 μg/kg body weight) was ingested by a healthy male volunteer. Urine samples were collected over a period of 46 h after the intake and analyzed for the hydrolysis product of glycidamide (GA), 2,3-dihydroxy-propionamide (OH-PA), a

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