562246

4-(2-Tetrahydro-2H-pyranoxy)phenylmagnesiumbromid -Lösung

0.5 M in THF

• Empirische Formel (Hill-System): C₁₁H₁₃BrMgO₂
• CAS-Nummer: 36637-44-2
• Molekulargewicht: 281.43
• MDL-Nummer: MFCD03427254
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24880020
• NACRES: NA.22

Eigenschaften

• Eignung der Reaktion: reaction type: Grignard Reaction
• Konzentration: 0.5 M in THF
• bp: 65 °C
• Dichte: 0.961 g/mL at 25 °C
• Lagertemp.: 2-8°C
• SMILES String: Br[Mg]c1ccc(OC2CCCCO2)cc1
• InChI: 1S/C11H13O2.BrH.Mg/c1-2-6-10(7-3-1)13-11-8-4-5-9-12-11;;/h2-3,6-7,11H,4-5,8-9H2;1H;/q;;+1/p-1
• InChIKey: OHPUQUBYKZJOLY-UHFFFAOYSA-M

Beschreibung

Anwendung

4-(2-Tetrahydro-2H-pyranoxy)phenylmagnesium bromide can be used:

• In the preparation of C-2 and C-20-diaryl steroidal derivatives.
• As an intermediate in the synthesis of multiblock copolymers having fullerene backbone for possible applications in photovoltaic devices.

Rechtliche Hinweise

Product of Rieke^® Metals, Inc.

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS07
• Signalwort: Danger
• H-Sätze: H225,H302,H319,H335,H351
• P-Sätze: P210 - P280 - P301 + P312 + P330 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• Gefahreneinstufungen: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Zusätzliche Gefahrenhinweise: EUH019
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): <1.4 °F - closed cup
• Flammpunkt (°C): < -17 °C - closed cup