220809

Diethylzink -Lösung

15 wt. % in toluene

• Synonym(e): Zinkdiethyl
• Lineare Formel: (C₂H₅)₂Zn
• CAS-Nummer: 557-20-0
• Molekulargewicht: 123.51
• Beilstein: 3587207
• MDL-Nummer: MFCD00009021
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24853193
• NACRES: NA.22

Eigenschaften

• Form: liquid
• Konzentration: 15 wt. % in toluene
• Dichte: 0.915 g/mL at 25 °C
• SMILES String: CC[Zn]CC
• InChI: 1S/2C2H5.Zn/c2*1-2;/h2*1H2,2H3;
• InChIKey: HQWPLXHWEZZGKY-UHFFFAOYSA-N

Beschreibung

Anwendung

Employed together with CF₃I in a Rh(I) catalyzed preparation of α-trifluoromethyl ketones from α,ß-unsaturated ketones.[1] Promoter for the Wittig reaction of carbonyl compounds with dibromofluoroacetate and triphenylphosphine leading to α-fluroroacrylates.[2] Ni catalyzed coupling with cyclic anhydrides.[3]

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS05,GHS07,GHS09
• Signalwort: Danger
• H-Sätze: H225,H250,H260,H304,H314,H336,H361d,H373,H411
• P-Sätze: P210 - P231 + P232 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P370 + P378
• Gefahreneinstufungen: Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 1
• Zielorgane: Central nervous system
• Zusätzliche Gefahrenhinweise: EUH014
• Lagerklassenschlüssel: 4.2 - Pyrophoric and self-heating hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): 44.6 °F - closed cup
• Flammpunkt (°C): 7 °C - closed cup
• Persönliche Schutzausrüstung: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter