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401757

Sigma-Aldrich

Tetrahydrofurane

Tetrahydrofuran

≥99.9%, anhydrous, inhibitor-free

Synonyme(s) :

THF, Oxolane, Oxyde de butylène, Oxyde de tétraméthylène

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About This Item

Formule empirique (notation de Hill):
C4H8O
Numéro CAS:
Poids moléculaire :
72.11
Beilstein:
102391
Numéro CE :
Numéro MDL:
Code UNSPSC :
12191501
ID de substance PubChem :
Nomenclature NACRES :
NA.21
Qualité:
anhydrous
Essai:
≥99.9%
pb:
65-67 °C (lit.)
Pression de vapeur:
114 mmHg ( 15 °C)
143 mmHg ( 20 °C)
Le tarif et la disponibilité ne sont pas disponibles actuellement.

Nom du produit

Tetrahydrofurane, anhydrous, ≥99.9%, inhibitor-free

Qualité

anhydrous

Niveau de qualité

Densité de vapeur

2.5 (vs air)

Pression de vapeur

114 mmHg ( 15 °C)
143 mmHg ( 20 °C)

Essai

≥99.9%

Forme

liquid

Température d'inflammation spontanée

610 °F

Limite d'explosivité

1.8-11.8 %

Impuretés

≤20 ppm peroxide (as H2O2)
<0.002% water
<0.005% water (100 mL pkg)

Résidus d'évap.

<0.0005%

Indice de réfraction

n20/D 1.407 (lit.)

pH

~7

pb

65-67 °C (lit.)

Pf

−108 °C (lit.)

Solubilité

H2O: soluble

Densité

0.889 g/mL at 25 °C (lit.)

Chaîne SMILES 

C1CCOC1

InChI

1S/C4H8O/c1-2-4-5-3-1/h1-4H2

Clé InChI

WYURNTSHIVDZCO-UHFFFAOYSA-N

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Description générale

Le tétrahydrofurane (THF) est un éther cyclique saturé, susceptible de servir de biocarburant. Des études se sont penchées sur sa combustion.[1] Des rapports indiquent qu′il serait un meilleur promoteur que le 1,3 dioxolane dans la formation d′hydrates de CO2.[2]

Application

Le tétrahydrofurane a servi de solvant dans la formation de polymères diacétyléniques.[3]
Il peut être utilisé dans les situations suivantes :
  • Formation de butyrolactone (BTL) par une méthode d′oxydation verte.[4]
  • Modification de la surface d′un polystyrène par une solution aqueuse de THF selon un procédé de gonflement.[5]
  • Solvant pour la dépolymérisation de lignine en monomères phénoliques isolés.[6]

Conditionnement

Voir nos options de récipients consignés.

Autres remarques

Les récipients Pure-Pac® II requièrent l'utilisation de coupleurs de vanne Macro de Micro Matic, réf. Z560723, pour la distribution des solvants.

Informations légales

Pure-Pac is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictogrammes

FlameHealth hazardExclamation mark

Mention d'avertissement

Danger

Classification des risques

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

Organes cibles

Central nervous system, Respiratory system

Risques supp

Code de la classe de stockage

3 - Flammable liquids

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

-6.2 °F - closed cup

Point d'éclair (°C)

-21.2 °C - closed cup

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Certificats d'analyse (COA)

Lot/Batch Number

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Novel Diacetylinic Aryloxysilane Polymers: A New Thermally Cross-Linkable High Temperature Polymer System.
Drake K, et al.
Macromolecules, 46(11), 4370-4377 (2013)
Oxidation of tetrahydrofuran to butyrolactone catalyzed by iron-containing clay.
Ausavasukhi A and Sooknoi T.
Green Chemistry, 17(1), 435-441 (2015)
1,3 Dioxolane versus tetrahydrofuran as promoters for CO2-hydrate formation: Thermodynamics properties, and kinetics in presence of sodium dodecyl sulfate.
Torre JP, et al.
Chemical Engineering Science, 126, 688-697 (2015)
An efficient and economical process for lignin depolymerization in biomass-derived solvent tetrahydrofuran.
Long J, et al.
Bioresource Technology, 154, 10-17 (2014)

Articles

Tandem hydroboration Suzuki Coupling both intermolecular and intramolecular gave diverse alkyl substituted products dppf

Substances are said to be miscible in one another if they dissolve to form a uniform solution. Bookmark or download our miscibility table for common lab solvents.

Des substances sont dites miscibles si elles se dissolvent l'une dans l'autre en formant une solution uniforme. Ajoutez à vos marque-pages ou téléchargez notre tableau de miscibilité incluant les solvants de laboratoire courants.

Questions

1–7 of 7 Questions  
  1. Is this product (401757-1L) considered UPLC grade THF (without inhibiter)?

    1 answer
    1. No, this product is not considered to be a UPLC grade. The purity is determined by GC.

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  4. Are the products 227056-1L N,N-Dimethylformamide and 401757-1L Tetrahydrofuran come with a SureSeal Cap?

    1 answer
    1. Yes, according to the material BOM. 401757-1L is 10mm and 227056-1L is 5mm

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  5. What is the material of the Sure/Seal septum? Does it contain silicon? Is there a risk of parts of it falling into the product?

    1 answer
    1. The Sure/Seal septum is made of a robust, proprietary elastomer that does not allow any particulates to contaminate the product contents. For frequent access , it is recommended to puncture the septum in a square pattern around the border of the hole cap. This pattern may be gradually reduced until reaching the center of the septum.

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  6. Which type of syringes or needles do you recommend for extracting products from a Sure/Seal bottle?

    1 answer
    1. Products packaged in Sure/Seal bottles may be accessed using a non-coring needle of an 18 or lower gauge. This item is an 18 gauge, 12 inch needle with a slightly curved tip to prevent coring.
      Please see the link below to review product Z101141, as an example.
      https://www.sigmaaldrich.com/product/aldrich/z101141

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  7. Hi! For this product 401757-1L, does it come automatically with a Sure-Seal cap?

    1 answer
    1. Product 401757-1L is packaged in an amber glass bottle with a Sure/Seal™ cap. Please see the link below for additional information regarding the Sure/Seal system: https://www.sigmaaldrich.com/technical-documents/technical-article/chemistry-and-synthesis/organic-reaction-toolbox/sureseal

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