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1,1,1,3,3,3-Hexafluoro-2-propanol

1,1,1,3,3,3-Hexafluoro-2-propanol
1 of 1 reviewers received a sample product or took part in a promotion

for LC-MS LiChropur

Sinônimo(s):

HFP, Hexafluoroisopropanol

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About This Item

Fórmula linear:
(CF3)2CHOH
Número CAS:
Peso molecular:
168.04
Beilstein:
1841007
Número MDL:
Código UNSPSC:
12352104
NACRES:
NA.21
Preço e disponibilidade não estão disponíveis no momento.

Ensaio

≥99.8% (GC)

Formulário

liquid

qualidade

for LC-MS LiChropur

Impurezas

≤0.02% water

índice de refração

n20/D 1.275 (lit.)

p.e.

59 °C (lit.)

pf

−4 °C (lit.)

densidade

1.596 g/mL at 25 °C (lit.)

traços de cátion

Al: ≤0.5 ppm
Ca: ≤0.5 ppm
Cu: ≤0.02 ppm
Fe: ≤0.1 ppm
K: ≤2 ppm
Mg: ≤0.1 ppm
Na: ≤10 ppm

adequação

passes test for LC-MS (ESI/APCI pos. < 10 ppb)

cadeia de caracteres SMILES

OC(C(F)(F)F)C(F)(F)F

InChI

1S/C3H2F6O/c4-2(5,6)1(10)3(7,8)9/h1,10H

chave InChI

BYEAHWXPCBROCE-UHFFFAOYSA-N

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Descrição geral

1,1,1,3,3,3-Hexafluoro-2-propanol(HFIP) is a thermally stable, highly polar, UV-transparent solvent that is misciblewith water and many polar organic solvents. It is used as a mobile phaseadditive in liquid chromatography-mass spectrometry (LC-MS) method to improveseparation and detection.[1][2]

Aplicação

1,1,1,3,3,3-Hexafluoro-2-propanol can be used as a:
  • Buffer additive for LC-ESI-MS to separate acidic and basic compounds.[3]
  • Eluent additive in the UHPLC-MS/MS method to improve the chromatographic separation of basic and zwitterionic compounds.

Informações legais

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Pictogramas

Health hazardCorrosion

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Eye Dam. 1 - Repr. 2 - Skin Corr. 1A - STOT RE 2 Oral

Órgãos-alvo

Central nervous system

Código de classe de armazenamento

8A - Combustible corrosive hazardous materials

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

No data available

Ponto de fulgor (°C)

No data available


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Certificados de análise (COA)

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Encontre a documentação dos produtos que você adquiriu recentemente na biblioteca de documentos.

Visite a Biblioteca de Documentos

1, 1, 1, 3, 3, 3-Hexafluoro-2-propanol
Phillips AJ and Roach JJ
e-EROS Encyclopedia of Reagents for Organic Synthesis, 1-9 (2001)
Retention mechanisms of acidic and basic analytes on the Pentafluorophenyl stationary phase using fluorinated eluent additives
Lossmann K, et al.
Journal of Chromatography A, 1666, 462850-462850 (2022)
Fluoroalcohols as novel buffer components for basic buffer solutions for liquid chromatography electrospray ionization mass spectrometry: retention mechanisms
Kipper K, et al.
Journal of Chromatography A, 1218(45), 8175-8180 (2011)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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